Determinación de los parámetros cinéticos en la pirólisis del pino ciprés Determination of kinetics parameters in the pyrolysis of cypres pine

<abstract language="eng">The study of pyrolysis is gaining increasing importance, since it is the first step in the gasification or combustion process. In this study, pyrolysis experiments of cypress pine were carried out in a thermogravimetric analyzer at six different heating rates...

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Bibliographic Details
Main Authors: Nancy Acelas Soto, Wilson Ruíz Machado, Diana López López
Format: Article
Language:English
Published: Sociedade Brasileira de Química 2010-01-01
Series:Química Nova
Subjects:
TGA
Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422010000700014
Description
Summary:<abstract language="eng">The study of pyrolysis is gaining increasing importance, since it is the first step in the gasification or combustion process. In this study, pyrolysis experiments of cypress pine were carried out in a thermogravimetric analyzer at six different heating rates between 5 and 40 ºC / min. Kinetics parameters of pine were determined from TGA by using the differential and the maximum speed methods. Additionally, the distribution of activation energies was also carried out finding the values of 113.57 and 157.32 kJ/mol, which are in the range of activation energies reported for hemicellulose and cellulose, respectively, main components of wood.
ISSN:0100-4042
1678-7064