Synthesis, crystal structure and Raman spectrum of K2[(Pt2)(HPO4)4(H2O)2] containing (Pt2)6+ ions

Synthesis, crystal structure and Raman spectrum of K2[(Pt2)(HPO4)4(H2O)2] containing (Pt2)6+ ions

In the crystal structure of the acid platinum phosphate dipotassium di-μ-hydrogenphosphato-bis[aquaplatinum(III)](Pt—Pt), K2[Pt2(HPO4)4(H2O)2], the (Pt2)6+ dumbbells within the paddle-wheel complex show Pt—Pt distances of 2.4944 (5) and 2.4892&a...

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Format: Article
Language:English
Published: International Union of Crystallography 2009-03-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809005601
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spelling doaj-7fd8dcd7356641cba2c26864ace02b902020-11-24T22:21:18ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-03-01653i18i1910.1107/S1600536809005601Synthesis, crystal structure and Raman spectrum of K2[(Pt2)(HPO4)4(H2O)2] containing (Pt2)6+ ionsIn the crystal structure of the acid platinum phosphate dipotassium di-μ-hydrogenphosphato-bis[aquaplatinum(III)](Pt—Pt), K2[Pt2(HPO4)4(H2O)2], the (Pt2)6+ dumbbells within the paddle-wheel complex show Pt—Pt distances of 2.4944 (5) and 2.4892 (5) Å. The pottassium ions are seven-fold coordinated by hydrogenphosphate groups. In the crystal, O—H...O hydrogen bonds help to establish the packing. The Raman spectrum was recorded. http://scripts.iucr.org/cgi-bin/paper?S1600536809005601
collection DOAJ
language English
format Article
sources DOAJ
title Synthesis, crystal structure and Raman spectrum of K2[(Pt2)(HPO4)4(H2O)2] containing (Pt2)6+ ions
spellingShingle Synthesis, crystal structure and Raman spectrum of K2[(Pt2)(HPO4)4(H2O)2] containing (Pt2)6+ ions
Acta Crystallographica Section E
title_short Synthesis, crystal structure and Raman spectrum of K2[(Pt2)(HPO4)4(H2O)2] containing (Pt2)6+ ions
title_full Synthesis, crystal structure and Raman spectrum of K2[(Pt2)(HPO4)4(H2O)2] containing (Pt2)6+ ions
title_fullStr Synthesis, crystal structure and Raman spectrum of K2[(Pt2)(HPO4)4(H2O)2] containing (Pt2)6+ ions
title_full_unstemmed Synthesis, crystal structure and Raman spectrum of K2[(Pt2)(HPO4)4(H2O)2] containing (Pt2)6+ ions
title_sort synthesis, crystal structure and raman spectrum of k2[(pt2)(hpo4)4(h2o)2] containing (pt2)6+ ions
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-03-01
description In the crystal structure of the acid platinum phosphate dipotassium di-μ-hydrogenphosphato-bis[aquaplatinum(III)](Pt—Pt), K2[Pt2(HPO4)4(H2O)2], the (Pt2)6+ dumbbells within the paddle-wheel complex show Pt—Pt distances of 2.4944 (5) and 2.4892 (5) Å. The pottassium ions are seven-fold coordinated by hydrogenphosphate groups. In the crystal, O—H...O hydrogen bonds help to establish the packing. The Raman spectrum was recorded.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809005601
_version_ 1725771747087613952

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