Synthesis, crystal structure and Raman spectrum of K2[(Pt2)(HPO4)4(H2O)2] containing (Pt2)6+ ions

Synthesis, crystal structure and Raman spectrum of K2[(Pt2)(HPO4)4(H2O)2] containing (Pt2)6+ ions

In the crystal structure of the acid platinum phosphate dipotassium di-μ-hydrogenphosphato-bis[aquaplatinum(III)](Pt—Pt), K2[Pt2(HPO4)4(H2O)2], the (Pt2)6+ dumbbells within the paddle-wheel complex show Pt—Pt distances of 2.4944 (5) and 2.4892&a...

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Bibliographic Details
Format: Article
Language:English
Published: International Union of Crystallography 2009-03-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809005601
Description
Summary:In the crystal structure of the acid platinum phosphate dipotassium di-μ-hydrogenphosphato-bis[aquaplatinum(III)](Pt—Pt), K2[Pt2(HPO4)4(H2O)2], the (Pt2)6+ dumbbells within the paddle-wheel complex show Pt—Pt distances of 2.4944 (5) and 2.4892 (5) Å. The pottassium ions are seven-fold coordinated by hydrogenphosphate groups. In the crystal, O—H...O hydrogen bonds help to establish the packing. The Raman spectrum was recorded.
ISSN:1600-5368

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