Bis(ethanol-κO)bis(1-ferrocenyl-4,4,4-trifluorobutane-1,3-dionato-κ2O,O′)nickel(II)
In the title compound, [NiFe2(C5H5)(C9H5F3O2)2(C2H6O)2], the central NiII ion is observed in an octahedral coordination environment. The chelating β-diketonate ligands are substituted by ferrocene, a lipophilic organometallic moiety. The ferrocene groups have the normal geometry, with eclipsed cyclo...
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International Union of Crystallography
2021-07-01
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314621006933 |
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doaj-7fa32a49a15a4ef08ee739f742762a292021-08-05T14:33:59ZengInternational Union of CrystallographyIUCrData2414-31462021-07-0167x21069310.1107/S2414314621006933bh4064Bis(ethanol-κO)bis(1-ferrocenyl-4,4,4-trifluorobutane-1,3-dionato-κ2O,O′)nickel(II)Wenqing Su0Tianyue Fu1Zhongwei Xu2Department of Chemistry, Anhui University, Hefei, Anhui 230039, People's Republic of ChinaDepartment of Chemistry, Anhui University, Hefei, Anhui 230039, People's Republic of ChinaDepartment of Chemistry, Anhui University, Hefei, Anhui 230039, People's Republic of ChinaIn the title compound, [NiFe2(C5H5)(C9H5F3O2)2(C2H6O)2], the central NiII ion is observed in an octahedral coordination environment. The chelating β-diketonate ligands are substituted by ferrocene, a lipophilic organometallic moiety. The ferrocene groups have the normal geometry, with eclipsed cyclopentadiene rings. Coordinated ethanol molecules are engaged in intermolecular hydrogen bonds, and the crystal is further stabilized by weak C—H...F and C—H...π contacts.http://scripts.iucr.org/cgi-bin/paper?S2414314621006933crystal structureferrocenenickel |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Wenqing Su Tianyue Fu Zhongwei Xu |
| spellingShingle |
Wenqing Su Tianyue Fu Zhongwei Xu Bis(ethanol-κO)bis(1-ferrocenyl-4,4,4-trifluorobutane-1,3-dionato-κ2O,O′)nickel(II) IUCrData crystal structure ferrocene nickel |
| author_facet |
Wenqing Su Tianyue Fu Zhongwei Xu |
| author_sort |
Wenqing Su |
| title |
Bis(ethanol-κO)bis(1-ferrocenyl-4,4,4-trifluorobutane-1,3-dionato-κ2O,O′)nickel(II) |
| title_short |
Bis(ethanol-κO)bis(1-ferrocenyl-4,4,4-trifluorobutane-1,3-dionato-κ2O,O′)nickel(II) |
| title_full |
Bis(ethanol-κO)bis(1-ferrocenyl-4,4,4-trifluorobutane-1,3-dionato-κ2O,O′)nickel(II) |
| title_fullStr |
Bis(ethanol-κO)bis(1-ferrocenyl-4,4,4-trifluorobutane-1,3-dionato-κ2O,O′)nickel(II) |
| title_full_unstemmed |
Bis(ethanol-κO)bis(1-ferrocenyl-4,4,4-trifluorobutane-1,3-dionato-κ2O,O′)nickel(II) |
| title_sort |
bis(ethanol-κo)bis(1-ferrocenyl-4,4,4-trifluorobutane-1,3-dionato-κ2o,o′)nickel(ii) |
| publisher |
International Union of Crystallography |
| series |
IUCrData |
| issn |
2414-3146 |
| publishDate |
2021-07-01 |
| description |
In the title compound, [NiFe2(C5H5)(C9H5F3O2)2(C2H6O)2], the central NiII ion is observed in an octahedral coordination environment. The chelating β-diketonate ligands are substituted by ferrocene, a lipophilic organometallic moiety. The ferrocene groups have the normal geometry, with eclipsed cyclopentadiene rings. Coordinated ethanol molecules are engaged in intermolecular hydrogen bonds, and the crystal is further stabilized by weak C—H...F and C—H...π contacts. |
| topic |
crystal structure ferrocene nickel |
| url |
http://scripts.iucr.org/cgi-bin/paper?S2414314621006933 |
| work_keys_str_mv |
AT wenqingsu bisethanolkobis1ferrocenyl444trifluorobutane13dionatok2oonickelii AT tianyuefu bisethanolkobis1ferrocenyl444trifluorobutane13dionatok2oonickelii AT zhongweixu bisethanolkobis1ferrocenyl444trifluorobutane13dionatok2oonickelii |
| _version_ |
1721220389543084032 |