Bis(ethanol-κO)bis(1-ferrocenyl-4,4,4-trifluorobutane-1,3-dionato-κ2O,O′)nickel(II)

Bis(ethanol-κO)bis(1-ferrocenyl-4,4,4-trifluorobutane-1,3-dionato-κ2O,O′)nickel(II)

In the title compound, [NiFe2(C5H5)(C9H5F3O2)2(C2H6O)2], the central NiII ion is observed in an octahedral coordination environment. The chelating β-diketonate ligands are substituted by ferrocene, a lipophilic organometallic moiety. The ferrocene groups have the normal geometry, with eclipsed cyclo...

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Bibliographic Details
Main Authors: Wenqing Su, Tianyue Fu, Zhongwei Xu
Format: Article
Language:English
Published: International Union of Crystallography 2021-07-01
Series:IUCrData
Subjects:
crystal structure
ferrocene
nickel
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2414314621006933
Description
Summary:In the title compound, [NiFe2(C5H5)(C9H5F3O2)2(C2H6O)2], the central NiII ion is observed in an octahedral coordination environment. The chelating β-diketonate ligands are substituted by ferrocene, a lipophilic organometallic moiety. The ferrocene groups have the normal geometry, with eclipsed cyclopentadiene rings. Coordinated ethanol molecules are engaged in intermolecular hydrogen bonds, and the crystal is further stabilized by weak C—H...F and C—H...π contacts.
ISSN:2414-3146

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