Poly[[μ4-naphthalene-1,4-dicarboxylato-κ4O:O′:O′′:O′′′-μ2-naphthalene-1,4-dicarboxylato-κ4O,O′:O′′,O′′′-bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8)dimanganese(II)] N,N-dimethylformamide solvate]

Poly[[μ4-naphthalene-1,4-dicarboxylato-κ4O:O′:O′′:O′′′-μ2-naphthalene-1,4-dicarboxylato-κ4O,O′:O′′,O′′′-bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8)dimanganese(II)] N,N-dimethylformamide solvate]

One of the two 1,4-dicarboxylate dianions in the title compound, [Mn2(C12H6O4)2(C19H12N4)2]·C3H7NO, uses its two carboxylate groups to chelate two N-heterocycle-chelated Mn atoms; the other 1,4-dicarboxylate dianion binds to four such metal centers. The octahedrally coordinated Mn atoms are...

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Main Authors: Seik Weng Ng, Mao-Liang Xu, Yang Liu, Heng-Da Li
Format: Article
Language:English
Published: International Union of Crystallography 2008-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808010787
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spelling doaj-7f6e32f9a33d45efadb4b86b17131c392020-11-25T02:19:12ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-05-01645m704m70510.1107/S1600536808010787Poly[[μ4-naphthalene-1,4-dicarboxylato-κ4O:O′:O′′:O′′′-μ2-naphthalene-1,4-dicarboxylato-κ4O,O′:O′′,O′′′-bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8)dimanganese(II)] N,N-dimethylformamide solvate]Seik Weng NgMao-Liang XuYang LiuHeng-Da LiOne of the two 1,4-dicarboxylate dianions in the title compound, [Mn2(C12H6O4)2(C19H12N4)2]·C3H7NO, uses its two carboxylate groups to chelate two N-heterocycle-chelated Mn atoms; the other 1,4-dicarboxylate dianion binds to four such metal centers. The octahedrally coordinated Mn atoms are linked through the two dianions into a layer motif; the dimethylformamide molecules occupy the spaces between adjacent layers. Ten C atoms and attached H atoms of one dianion are disordered equally over two positions.http://scripts.iucr.org/cgi-bin/paper?S1600536808010787
collection DOAJ
language English
format Article
sources DOAJ
author Seik Weng Ng
Mao-Liang Xu
Yang Liu
Heng-Da Li
spellingShingle Seik Weng Ng
Mao-Liang Xu
Yang Liu
Heng-Da Li
Poly[[μ4-naphthalene-1,4-dicarboxylato-κ4O:O′:O′′:O′′′-μ2-naphthalene-1,4-dicarboxylato-κ4O,O′:O′′,O′′′-bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8)dimanganese(II)] N,N-dimethylformamide solvate]
Acta Crystallographica Section E
author_facet Seik Weng Ng
Mao-Liang Xu
Yang Liu
Heng-Da Li
author_sort Seik Weng Ng
title Poly[[μ4-naphthalene-1,4-dicarboxylato-κ4O:O′:O′′:O′′′-μ2-naphthalene-1,4-dicarboxylato-κ4O,O′:O′′,O′′′-bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8)dimanganese(II)] N,N-dimethylformamide solvate]
title_short Poly[[μ4-naphthalene-1,4-dicarboxylato-κ4O:O′:O′′:O′′′-μ2-naphthalene-1,4-dicarboxylato-κ4O,O′:O′′,O′′′-bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8)dimanganese(II)] N,N-dimethylformamide solvate]
title_full Poly[[μ4-naphthalene-1,4-dicarboxylato-κ4O:O′:O′′:O′′′-μ2-naphthalene-1,4-dicarboxylato-κ4O,O′:O′′,O′′′-bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8)dimanganese(II)] N,N-dimethylformamide solvate]
title_fullStr Poly[[μ4-naphthalene-1,4-dicarboxylato-κ4O:O′:O′′:O′′′-μ2-naphthalene-1,4-dicarboxylato-κ4O,O′:O′′,O′′′-bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8)dimanganese(II)] N,N-dimethylformamide solvate]
title_full_unstemmed Poly[[μ4-naphthalene-1,4-dicarboxylato-κ4O:O′:O′′:O′′′-μ2-naphthalene-1,4-dicarboxylato-κ4O,O′:O′′,O′′′-bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2N7,N8)dimanganese(II)] N,N-dimethylformamide solvate]
title_sort poly[[μ4-naphthalene-1,4-dicarboxylato-κ4o:o′:o′′:o′′′-μ2-naphthalene-1,4-dicarboxylato-κ4o,o′:o′′,o′′′-bis(2-phenyl-1h-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ2n7,n8)dimanganese(ii)] n,n-dimethylformamide solvate]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-05-01
description One of the two 1,4-dicarboxylate dianions in the title compound, [Mn2(C12H6O4)2(C19H12N4)2]·C3H7NO, uses its two carboxylate groups to chelate two N-heterocycle-chelated Mn atoms; the other 1,4-dicarboxylate dianion binds to four such metal centers. The octahedrally coordinated Mn atoms are linked through the two dianions into a layer motif; the dimethylformamide molecules occupy the spaces between adjacent layers. Ten C atoms and attached H atoms of one dianion are disordered equally over two positions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808010787
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AT maoliangxu poly9564naphthalene14dicarboxylato9544oo8242o82428242o8242824282429562naphthalene14dicarboxylato9544oo8242o82428242o824282428242bis2phenyl1h1378tetraazacyclopentalphenanthrene9542n7n8dimanganeseiinndimethylformamidesolvate
AT yangliu poly9564naphthalene14dicarboxylato9544oo8242o82428242o8242824282429562naphthalene14dicarboxylato9544oo8242o82428242o824282428242bis2phenyl1h1378tetraazacyclopentalphenanthrene9542n7n8dimanganeseiinndimethylformamidesolvate
AT hengdali poly9564naphthalene14dicarboxylato9544oo8242o82428242o8242824282429562naphthalene14dicarboxylato9544oo8242o82428242o824282428242bis2phenyl1h1378tetraazacyclopentalphenanthrene9542n7n8dimanganeseiinndimethylformamidesolvate
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