{2-[(2-Carbamothiolylhydrazin-1-ylidene-κ2N1,S)methyl]-6-hydroxyphenolato-κO1}(triphenylphosphine-κP)nickel(II) chloride
The deprotonated Schiff base ligand in the title compound, [Ni(C8H8N3O2S)(C18H15P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated Ni atom, which exists in a distorted square-planar geometry. The hydroxy group forms an intramolecular O—H...O hydrogen bond. The tw...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810031065 |