{2-[(2-Carbamothiolylhydrazin-1-ylidene-κ2N1,S)methyl]-6-hydroxyphenolato-κO1}(triphenylphosphine-κP)nickel(II) chloride

{2-[(2-Carbamothiolylhydrazin-1-ylidene-κ2N1,S)methyl]-6-hydroxyphenolato-κO1}(triphenylphosphine-κP)nickel(II) chloride

The deprotonated Schiff base ligand in the title compound, [Ni(C8H8N3O2S)(C18H15P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated Ni atom, which exists in a distorted square-planar geometry. The hydroxy group forms an intramolecular O—H...O hydrogen bond. The tw...

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Main Authors: Hana Bashir Shawish, Kong Wai Tan, M. Jamil Maah, Seik Weng Ng
Format: Article
Language:English
Published: International Union of Crystallography 2010-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810031065
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spelling doaj-7f45dca5790946f3834dec8bd6fef56f2020-11-25T02:24:30ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-09-01669m1074m107410.1107/S1600536810031065{2-[(2-Carbamothiolylhydrazin-1-ylidene-κ2N1,S)methyl]-6-hydroxyphenolato-κO1}(triphenylphosphine-κP)nickel(II) chlorideHana Bashir ShawishKong Wai TanM. Jamil MaahSeik Weng NgThe deprotonated Schiff base ligand in the title compound, [Ni(C8H8N3O2S)(C18H15P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated Ni atom, which exists in a distorted square-planar geometry. The hydroxy group forms an intramolecular O—H...O hydrogen bond. The two amino groups of the cation are hydrogen-bond donors to the chloride anion; the hydrogen bonds generate a chain structure running along the b axis. http://scripts.iucr.org/cgi-bin/paper?S1600536810031065
collection DOAJ
language English
format Article
sources DOAJ
author Hana Bashir Shawish
Kong Wai Tan
M. Jamil Maah
Seik Weng Ng
spellingShingle Hana Bashir Shawish
Kong Wai Tan
M. Jamil Maah
Seik Weng Ng
{2-[(2-Carbamothiolylhydrazin-1-ylidene-κ2N1,S)methyl]-6-hydroxyphenolato-κO1}(triphenylphosphine-κP)nickel(II) chloride
Acta Crystallographica Section E
author_facet Hana Bashir Shawish
Kong Wai Tan
M. Jamil Maah
Seik Weng Ng
author_sort Hana Bashir Shawish
title {2-[(2-Carbamothiolylhydrazin-1-ylidene-κ2N1,S)methyl]-6-hydroxyphenolato-κO1}(triphenylphosphine-κP)nickel(II) chloride
title_short {2-[(2-Carbamothiolylhydrazin-1-ylidene-κ2N1,S)methyl]-6-hydroxyphenolato-κO1}(triphenylphosphine-κP)nickel(II) chloride
title_full {2-[(2-Carbamothiolylhydrazin-1-ylidene-κ2N1,S)methyl]-6-hydroxyphenolato-κO1}(triphenylphosphine-κP)nickel(II) chloride
title_fullStr {2-[(2-Carbamothiolylhydrazin-1-ylidene-κ2N1,S)methyl]-6-hydroxyphenolato-κO1}(triphenylphosphine-κP)nickel(II) chloride
title_full_unstemmed {2-[(2-Carbamothiolylhydrazin-1-ylidene-κ2N1,S)methyl]-6-hydroxyphenolato-κO1}(triphenylphosphine-κP)nickel(II) chloride
title_sort {2-[(2-carbamothiolylhydrazin-1-ylidene-κ2n1,s)methyl]-6-hydroxyphenolato-κo1}(triphenylphosphine-κp)nickel(ii) chloride
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-09-01
description The deprotonated Schiff base ligand in the title compound, [Ni(C8H8N3O2S)(C18H15P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated Ni atom, which exists in a distorted square-planar geometry. The hydroxy group forms an intramolecular O—H...O hydrogen bond. The two amino groups of the cation are hydrogen-bond donors to the chloride anion; the hydrogen bonds generate a chain structure running along the b axis.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810031065
work_keys_str_mv AT hanabashirshawish 22carbamothiolylhydrazin1ylideneamp9542n1smethyl6hydroxyphenolatoamp954o1triphenylphosphineamp954pnickeliichloride
AT kongwaitan 22carbamothiolylhydrazin1ylideneamp9542n1smethyl6hydroxyphenolatoamp954o1triphenylphosphineamp954pnickeliichloride
AT mjamilmaah 22carbamothiolylhydrazin1ylideneamp9542n1smethyl6hydroxyphenolatoamp954o1triphenylphosphineamp954pnickeliichloride
AT seikwengng 22carbamothiolylhydrazin1ylideneamp9542n1smethyl6hydroxyphenolatoamp954o1triphenylphosphineamp954pnickeliichloride
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