cis,trans-Dicarbonyldichlorido[2-(2-pyridyl)-1,8-naphthyridine-κN1,N2]ruthenium(II)

cis,trans-Dicarbonyldichlorido[2-(2-pyridyl)-1,8-naphthyridine-κN1,N2]ruthenium(II)

The asymmetric unit of the title compound, [RuCl2(C13H9N3)(CO)2], consists of four crystallographically independent RuII complexes. Each RuII atom is in a distorted octahedral environment coordinated by two carbonyl ligands, two Cl atoms and a chelating 2-(2-pyridyl)-1,8-naphthyridine (pynp) ligand....

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Main Authors: Takashi Hamada, Dai Oyama
Format: Article
Language:English
Published: International Union of Crystallography 2008-03-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808003188
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spelling doaj-7f345c7c30344f4a8e5294d55e24b95e2020-11-25T02:24:30ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-03-01643m442m44310.1107/S1600536808003188cis,trans-Dicarbonyldichlorido[2-(2-pyridyl)-1,8-naphthyridine-κN1,N2]ruthenium(II)Takashi HamadaDai OyamaThe asymmetric unit of the title compound, [RuCl2(C13H9N3)(CO)2], consists of four crystallographically independent RuII complexes. Each RuII atom is in a distorted octahedral environment coordinated by two carbonyl ligands, two Cl atoms and a chelating 2-(2-pyridyl)-1,8-naphthyridine (pynp) ligand. The carbonyl ligands are cis to each other, while the Cl atoms are trans. Relatively short interatomic distances (2.60–2.67 Å) between the uncoordinated N atom of pynp and the C atom of the carbonyl imply a donor–acceptor interaction between the pynp and carbonyl ligands.http://scripts.iucr.org/cgi-bin/paper?S1600536808003188
collection DOAJ
language English
format Article
sources DOAJ
author Takashi Hamada
Dai Oyama
spellingShingle Takashi Hamada
Dai Oyama
cis,trans-Dicarbonyldichlorido[2-(2-pyridyl)-1,8-naphthyridine-κN1,N2]ruthenium(II)
Acta Crystallographica Section E
author_facet Takashi Hamada
Dai Oyama
author_sort Takashi Hamada
title cis,trans-Dicarbonyldichlorido[2-(2-pyridyl)-1,8-naphthyridine-κN1,N2]ruthenium(II)
title_short cis,trans-Dicarbonyldichlorido[2-(2-pyridyl)-1,8-naphthyridine-κN1,N2]ruthenium(II)
title_full cis,trans-Dicarbonyldichlorido[2-(2-pyridyl)-1,8-naphthyridine-κN1,N2]ruthenium(II)
title_fullStr cis,trans-Dicarbonyldichlorido[2-(2-pyridyl)-1,8-naphthyridine-κN1,N2]ruthenium(II)
title_full_unstemmed cis,trans-Dicarbonyldichlorido[2-(2-pyridyl)-1,8-naphthyridine-κN1,N2]ruthenium(II)
title_sort cis,trans-dicarbonyldichlorido[2-(2-pyridyl)-1,8-naphthyridine-κn1,n2]ruthenium(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-03-01
description The asymmetric unit of the title compound, [RuCl2(C13H9N3)(CO)2], consists of four crystallographically independent RuII complexes. Each RuII atom is in a distorted octahedral environment coordinated by two carbonyl ligands, two Cl atoms and a chelating 2-(2-pyridyl)-1,8-naphthyridine (pynp) ligand. The carbonyl ligands are cis to each other, while the Cl atoms are trans. Relatively short interatomic distances (2.60–2.67 Å) between the uncoordinated N atom of pynp and the C atom of the carbonyl imply a donor–acceptor interaction between the pynp and carbonyl ligands.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808003188
work_keys_str_mv AT takashihamada cistransdicarbonyldichlorido22pyridyl18naphthyridine954n1n2rutheniumii
AT daioyama cistransdicarbonyldichlorido22pyridyl18naphthyridine954n1n2rutheniumii
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