Aqua(2,6-dihydroxybenzoato-κO1)bis(1,10-phenanthroline-κ2N,N′)manganese(II) 2,6-dihydroxybenzoate hemihydrate

Aqua(2,6-dihydroxybenzoato-κO1)bis(1,10-phenanthroline-κ2N,N′)manganese(II) 2,6-dihydroxybenzoate hemihydrate

In the complex cation of the title compound, [Mn(C7H5O4)(C12H8N2)2(H2O)](C7H5O4)·0.5H2O, the MnII atom has a six-coordinate octahedral environment defined by one carboxylate O atom belonging to a 2,6-dihydroxybenzoate (DHB) ligand, four N atoms from two chelating 1,10-phenanthroline mol...

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Main Authors: Quanwei Li, Li He, Hongxiao Jin
Format: Article
Language:English
Published: International Union of Crystallography 2012-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812022155
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spelling doaj-7f037904e6c94d7f9f811f1918612da12020-11-24T21:30:49ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-06-01686m798m79810.1107/S1600536812022155Aqua(2,6-dihydroxybenzoato-κO1)bis(1,10-phenanthroline-κ2N,N′)manganese(II) 2,6-dihydroxybenzoate hemihydrateQuanwei LiLi HeHongxiao JinIn the complex cation of the title compound, [Mn(C7H5O4)(C12H8N2)2(H2O)](C7H5O4)·0.5H2O, the MnII atom has a six-coordinate octahedral environment defined by one carboxylate O atom belonging to a 2,6-dihydroxybenzoate (DHB) ligand, four N atoms from two chelating 1,10-phenanthroline molecules and one water molecule. The lattice water molecule lies on a twofold rotation axis. Intramolecular O—H...O hydrogen bonds are present in the DHB anions and complex cations. Intermolecular O—H...O hydrogen bonds link two cations, two anions and one water molecule into a dimer. π–π interactions between the pyridine and benzene rings and between the benzene rings are also observed [centroid–centroid distances = 3.7774 (16), 3.7912 (16) and 3.7310 (17) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536812022155
collection DOAJ
language English
format Article
sources DOAJ
author Quanwei Li
Li He
Hongxiao Jin
spellingShingle Quanwei Li
Li He
Hongxiao Jin
Aqua(2,6-dihydroxybenzoato-κO1)bis(1,10-phenanthroline-κ2N,N′)manganese(II) 2,6-dihydroxybenzoate hemihydrate
Acta Crystallographica Section E
author_facet Quanwei Li
Li He
Hongxiao Jin
author_sort Quanwei Li
title Aqua(2,6-dihydroxybenzoato-κO1)bis(1,10-phenanthroline-κ2N,N′)manganese(II) 2,6-dihydroxybenzoate hemihydrate
title_short Aqua(2,6-dihydroxybenzoato-κO1)bis(1,10-phenanthroline-κ2N,N′)manganese(II) 2,6-dihydroxybenzoate hemihydrate
title_full Aqua(2,6-dihydroxybenzoato-κO1)bis(1,10-phenanthroline-κ2N,N′)manganese(II) 2,6-dihydroxybenzoate hemihydrate
title_fullStr Aqua(2,6-dihydroxybenzoato-κO1)bis(1,10-phenanthroline-κ2N,N′)manganese(II) 2,6-dihydroxybenzoate hemihydrate
title_full_unstemmed Aqua(2,6-dihydroxybenzoato-κO1)bis(1,10-phenanthroline-κ2N,N′)manganese(II) 2,6-dihydroxybenzoate hemihydrate
title_sort aqua(2,6-dihydroxybenzoato-κo1)bis(1,10-phenanthroline-κ2n,n′)manganese(ii) 2,6-dihydroxybenzoate hemihydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-06-01
description In the complex cation of the title compound, [Mn(C7H5O4)(C12H8N2)2(H2O)](C7H5O4)·0.5H2O, the MnII atom has a six-coordinate octahedral environment defined by one carboxylate O atom belonging to a 2,6-dihydroxybenzoate (DHB) ligand, four N atoms from two chelating 1,10-phenanthroline molecules and one water molecule. The lattice water molecule lies on a twofold rotation axis. Intramolecular O—H...O hydrogen bonds are present in the DHB anions and complex cations. Intermolecular O—H...O hydrogen bonds link two cations, two anions and one water molecule into a dimer. π–π interactions between the pyridine and benzene rings and between the benzene rings are also observed [centroid–centroid distances = 3.7774 (16), 3.7912 (16) and 3.7310 (17) Å].
url http://scripts.iucr.org/cgi-bin/paper?S1600536812022155
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AT lihe aqua26dihydroxybenzoatoamp954o1bis110phenanthrolineamp9542nnamp8242manganeseii26dihydroxybenzoatehemihydrate
AT hongxiaojin aqua26dihydroxybenzoatoamp954o1bis110phenanthrolineamp9542nnamp8242manganeseii26dihydroxybenzoatehemihydrate
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