REMOVAL OF FLUORIDE FROM SHATT AL-ARAB DRINKING WATER USING A NOVEL LOW COST MATERIAL

Drinking water contamination by fluoride component (F-) is considered as a main public problem in Basra city. The current study highlights on the removal of (F-) from drinking water using effective and low cost materials namely, banana shell and new technical that prepared from orange shell loaded...

Full description

Bibliographic Details
Main Author: Rusul N. Mohammed
Format: Article
Language:English
Published: Faculty of Engineering, University of Kufa 2018-08-01
Series:Mağallaẗ Al-kūfaẗ Al-handasiyyaẗ
Subjects:
Online Access:http://www.uokufa.edu.iq/journals/index.php/kje/article/view/7358
id doaj-7efbc6d638fb44b397771c6ea9b0a24c
record_format Article
spelling doaj-7efbc6d638fb44b397771c6ea9b0a24c2020-11-24T23:44:07ZengFaculty of Engineering, University of KufaMağallaẗ Al-kūfaẗ Al-handasiyyaẗ2071-55282523-00182018-08-0193116http://dx.doi.org/10.30572/2018/kje/090301REMOVAL OF FLUORIDE FROM SHATT AL-ARAB DRINKING WATER USING A NOVEL LOW COST MATERIALRusul N. Mohammed0Department of Chemical Engineering, College of Engineering, University of Basrah , Basrah city, Iraq.Drinking water contamination by fluoride component (F-) is considered as a main public problem in Basra city. The current study highlights on the removal of (F-) from drinking water using effective and low cost materials namely, banana shell and new technical that prepared from orange shell loaded with Zirconyl chloride solutions (Z-r4 (O-H)8 (H2-O)16] Cl8 (H2-O)12) to develop active adsorption sites for fluoride . High removal efficiency of 94.4 was achieved using fixed bed column loaded (Zc-dejr) under optimum operating conditions, 15.1ppm of feed concentration, 4.5 pH of feed solution and 4 cm of bed depth. Result of breakthrough profile showed that Thomas was coincided well with the experimental data. Two model, Pseude first order and Pseudo second order where used for finding the mechanism of adsorption kinetics for fluoride (F-) removal by two-bio adsorbents. The result showed that the external adsorption besides to the intra-particle diffusion contributes to the rate influential step. Lagmaier model gives the better result model for the two adsorbents then Temkin isotherm model (TIM). The final concentration of fluoride in treated water with the banana shell adsorbent was 1 mg/l, and with the new solution (Z-r4 (O-H)8(H2-O)16] Cl8 (H2-O)12 ) was 0.5 mg /l which is acceptable with the standard World Health Organization (WHO).http://www.uokufa.edu.iq/journals/index.php/kje/article/view/7358Fluoride Removal; Low Adsorbent; Drinking Water; Isothermal Model; Intra-particle diffusion.
collection DOAJ
language English
format Article
sources DOAJ
author Rusul N. Mohammed
spellingShingle Rusul N. Mohammed
REMOVAL OF FLUORIDE FROM SHATT AL-ARAB DRINKING WATER USING A NOVEL LOW COST MATERIAL
Mağallaẗ Al-kūfaẗ Al-handasiyyaẗ
Fluoride Removal; Low Adsorbent; Drinking Water; Isothermal Model; Intra-particle diffusion.
author_facet Rusul N. Mohammed
author_sort Rusul N. Mohammed
title REMOVAL OF FLUORIDE FROM SHATT AL-ARAB DRINKING WATER USING A NOVEL LOW COST MATERIAL
title_short REMOVAL OF FLUORIDE FROM SHATT AL-ARAB DRINKING WATER USING A NOVEL LOW COST MATERIAL
title_full REMOVAL OF FLUORIDE FROM SHATT AL-ARAB DRINKING WATER USING A NOVEL LOW COST MATERIAL
title_fullStr REMOVAL OF FLUORIDE FROM SHATT AL-ARAB DRINKING WATER USING A NOVEL LOW COST MATERIAL
title_full_unstemmed REMOVAL OF FLUORIDE FROM SHATT AL-ARAB DRINKING WATER USING A NOVEL LOW COST MATERIAL
title_sort removal of fluoride from shatt al-arab drinking water using a novel low cost material
publisher Faculty of Engineering, University of Kufa
series Mağallaẗ Al-kūfaẗ Al-handasiyyaẗ
issn 2071-5528
2523-0018
publishDate 2018-08-01
description Drinking water contamination by fluoride component (F-) is considered as a main public problem in Basra city. The current study highlights on the removal of (F-) from drinking water using effective and low cost materials namely, banana shell and new technical that prepared from orange shell loaded with Zirconyl chloride solutions (Z-r4 (O-H)8 (H2-O)16] Cl8 (H2-O)12) to develop active adsorption sites for fluoride . High removal efficiency of 94.4 was achieved using fixed bed column loaded (Zc-dejr) under optimum operating conditions, 15.1ppm of feed concentration, 4.5 pH of feed solution and 4 cm of bed depth. Result of breakthrough profile showed that Thomas was coincided well with the experimental data. Two model, Pseude first order and Pseudo second order where used for finding the mechanism of adsorption kinetics for fluoride (F-) removal by two-bio adsorbents. The result showed that the external adsorption besides to the intra-particle diffusion contributes to the rate influential step. Lagmaier model gives the better result model for the two adsorbents then Temkin isotherm model (TIM). The final concentration of fluoride in treated water with the banana shell adsorbent was 1 mg/l, and with the new solution (Z-r4 (O-H)8(H2-O)16] Cl8 (H2-O)12 ) was 0.5 mg /l which is acceptable with the standard World Health Organization (WHO).
topic Fluoride Removal; Low Adsorbent; Drinking Water; Isothermal Model; Intra-particle diffusion.
url http://www.uokufa.edu.iq/journals/index.php/kje/article/view/7358
work_keys_str_mv AT rusulnmohammed removaloffluoridefromshattalarabdrinkingwaterusinganovellowcostmaterial
_version_ 1725499995404107776