Li<sub>2</sub>(BH<sub>4</sub>)(NH<sub>2</sub>) Nanoconfined in SBA-15 as Solid-State Electrolyte for Lithium Batteries
Solid electrolytes with high Li-ion conductivity and electrochemical stability are very important for developing high-performance all-solid-state batteries. In this work, Li<sub>2</sub>(BH<sub>4</sub>)(NH<sub>2</sub>) is nanoconfined in the mesoporous silica molec...
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MDPI AG
2021-04-01
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| Series: | Nanomaterials |
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| Online Access: | https://www.mdpi.com/2079-4991/11/4/946 |
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doaj-7ef9dbae4cb0405a85cad1ab39c0e1ea2021-04-08T23:02:38ZengMDPI AGNanomaterials2079-49912021-04-011194694610.3390/nano11040946Li<sub>2</sub>(BH<sub>4</sub>)(NH<sub>2</sub>) Nanoconfined in SBA-15 as Solid-State Electrolyte for Lithium BatteriesQianyi Yang0Fuqiang Lu1Yulin Liu2Yijie Zhang3Xiujuan Wang4Yuepeng Pang5Shiyou Zheng6School of Material Science and Engineering, University of Shanghai for Science and Technology, Shanghai 200093, ChinaSchool of Material Science and Engineering, University of Shanghai for Science and Technology, Shanghai 200093, ChinaSchool of Material Science and Engineering, University of Shanghai for Science and Technology, Shanghai 200093, ChinaSchool of Material Science and Engineering, University of Shanghai for Science and Technology, Shanghai 200093, ChinaSchool of Material Science and Engineering, University of Shanghai for Science and Technology, Shanghai 200093, ChinaSchool of Material Science and Engineering, University of Shanghai for Science and Technology, Shanghai 200093, ChinaSchool of Material Science and Engineering, University of Shanghai for Science and Technology, Shanghai 200093, ChinaSolid electrolytes with high Li-ion conductivity and electrochemical stability are very important for developing high-performance all-solid-state batteries. In this work, Li<sub>2</sub>(BH<sub>4</sub>)(NH<sub>2</sub>) is nanoconfined in the mesoporous silica molecule sieve (SBA-15) using a melting–infiltration approach. This electrolyte exhibits excellent Li-ion conduction properties, achieving a Li-ion conductivity of 5.0 × 10<sup>−3</sup> S cm<sup>−1</sup> at 55 °C, an electrochemical stability window of 0 to 3.2 V and a Li-ion transference number of 0.97. In addition, this electrolyte can enable the stable cycling of Li|Li<sub>2</sub>(BH<sub>4</sub>)(NH<sub>2</sub>)@SBA-15|TiS<sub>2</sub> cells, which exhibit a reversible specific capacity of 150 mAh g<sup>−1</sup> with a Coulombic efficiency of 96% after 55 cycles.https://www.mdpi.com/2079-4991/11/4/946lithium borohydrideslithium amidesnanoconfinementsolid electrolytesall-solid-state batteries |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Qianyi Yang Fuqiang Lu Yulin Liu Yijie Zhang Xiujuan Wang Yuepeng Pang Shiyou Zheng |
| spellingShingle |
Qianyi Yang Fuqiang Lu Yulin Liu Yijie Zhang Xiujuan Wang Yuepeng Pang Shiyou Zheng Li<sub>2</sub>(BH<sub>4</sub>)(NH<sub>2</sub>) Nanoconfined in SBA-15 as Solid-State Electrolyte for Lithium Batteries Nanomaterials lithium borohydrides lithium amides nanoconfinement solid electrolytes all-solid-state batteries |
| author_facet |
Qianyi Yang Fuqiang Lu Yulin Liu Yijie Zhang Xiujuan Wang Yuepeng Pang Shiyou Zheng |
| author_sort |
Qianyi Yang |
| title |
Li<sub>2</sub>(BH<sub>4</sub>)(NH<sub>2</sub>) Nanoconfined in SBA-15 as Solid-State Electrolyte for Lithium Batteries |
| title_short |
Li<sub>2</sub>(BH<sub>4</sub>)(NH<sub>2</sub>) Nanoconfined in SBA-15 as Solid-State Electrolyte for Lithium Batteries |
| title_full |
Li<sub>2</sub>(BH<sub>4</sub>)(NH<sub>2</sub>) Nanoconfined in SBA-15 as Solid-State Electrolyte for Lithium Batteries |
| title_fullStr |
Li<sub>2</sub>(BH<sub>4</sub>)(NH<sub>2</sub>) Nanoconfined in SBA-15 as Solid-State Electrolyte for Lithium Batteries |
| title_full_unstemmed |
Li<sub>2</sub>(BH<sub>4</sub>)(NH<sub>2</sub>) Nanoconfined in SBA-15 as Solid-State Electrolyte for Lithium Batteries |
| title_sort |
li<sub>2</sub>(bh<sub>4</sub>)(nh<sub>2</sub>) nanoconfined in sba-15 as solid-state electrolyte for lithium batteries |
| publisher |
MDPI AG |
| series |
Nanomaterials |
| issn |
2079-4991 |
| publishDate |
2021-04-01 |
| description |
Solid electrolytes with high Li-ion conductivity and electrochemical stability are very important for developing high-performance all-solid-state batteries. In this work, Li<sub>2</sub>(BH<sub>4</sub>)(NH<sub>2</sub>) is nanoconfined in the mesoporous silica molecule sieve (SBA-15) using a melting–infiltration approach. This electrolyte exhibits excellent Li-ion conduction properties, achieving a Li-ion conductivity of 5.0 × 10<sup>−3</sup> S cm<sup>−1</sup> at 55 °C, an electrochemical stability window of 0 to 3.2 V and a Li-ion transference number of 0.97. In addition, this electrolyte can enable the stable cycling of Li|Li<sub>2</sub>(BH<sub>4</sub>)(NH<sub>2</sub>)@SBA-15|TiS<sub>2</sub> cells, which exhibit a reversible specific capacity of 150 mAh g<sup>−1</sup> with a Coulombic efficiency of 96% after 55 cycles. |
| topic |
lithium borohydrides lithium amides nanoconfinement solid electrolytes all-solid-state batteries |
| url |
https://www.mdpi.com/2079-4991/11/4/946 |
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