Eco-Friendly Synthesis of Water-Glass-Based Silica Aerogels via Catechol-Based Modifier

• Main Authors: Hyeonjung Kim, Kangyong Kim, Hyunhong Kim, Doo Jin Lee, Jongnam Park
• Format: Article
• Language: English
• Published: MDPI AG 2020-12-01
• Series: Nanomaterials
• Subjects: water-glass aerogel; catechol coating; eco-friendly; trimethylchlorosilane substitute; ambient pressure drying; thermal insulation
• Online Access: https://www.mdpi.com/2079-4991/10/12/2406

Silica aerogels have attracted much attention owing to their excellent thermal insulation properties. However, the conventional synthesis of silica aerogels involves the use of expensive and toxic alkoxide precursors and surface modifiers such as trimethylchlorosilane. In this study, cost-effective water-glass silica aerogels were synthesized using an eco-friendly catechol derivative surface modifier instead of trimethylchlorosilane. Polydopamine was introduced to increase adhesion to the SiO₂ surface. The addition of 4-<i>tert</i>-butyl catechol and hexylamine imparted hydrophobicity to the surface and suppressed the polymerization of the polydopamine. After an ambient pressure drying process, catechol-modified aerogel exhibited a specific surface area of 377 m²/g and an average pore diameter of approximately 21 nm. To investigate their thermal conductivities, glass wool sheets were impregnated with catechol-modified aerogel. The thermal conductivity was 40.4 mWm⁻¹K⁻¹, which is lower than that of xerogel at 48.7 mWm⁻¹K⁻¹. Thus, by precisely controlling the catechol coating in the mesoporous framework, an eco-friendly synthetic method for aerogel preparation is proposed.