Base-Mediated Claisen Rearrangement of CF<sub>3</sub>-Containing Bisallyl Ethers

Base-Mediated Claisen Rearrangement of CF<sub>3</sub>-Containing Bisallyl Ethers

We have previously clarified that the strongly electron-withdrawing CF<sub>3</sub> group nicely affected the base-mediated proton shift of CF<sub>3</sub>-containing propargylic or allylic alcohols to afford the corresponding α,β-unsaturated or saturated ketones, respectively,...

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Bibliographic Details
Main Authors: Yoko Hamada, Rio Matsunaga, Tomoko Kawasaki-Takasuka, Takashi Yamazaki
Format: Article
Language:English
Published: MDPI AG 2021-07-01
Series:Molecules
Subjects:
Claisen rearrangement
isomerization
trifluoromethyl
Cieplak rule
Online Access:https://www.mdpi.com/1420-3049/26/14/4365

Internet

https://www.mdpi.com/1420-3049/26/14/4365

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