Diaquabis(1,10-phenanthroline)magnesium dichromate(VI) 1,10-phenanthroline disolvate

Diaquabis(1,10-phenanthroline)magnesium dichromate(VI) 1,10-phenanthroline disolvate

In the title compound, [Mg(C12H8N2)2(H2O)2][Cr2O7]·2C12H8N2, the cation and anion are situated on a twofold rotation axis. The MgII ion is coordinated by four N atoms from two 1,10-phenanthroline ligands and two O atoms from coordinated water molecules in a distorted octahedral geometry...

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Main Authors: Hai-Xing Liu, Gui-Ying Dong, Zhi-Hong Ma, Guang-Hua Cui
Format: Article
Language:English
Published: International Union of Crystallography 2009-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809030128
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spelling doaj-7e430aeef11a417c9974f524b3b883a52020-11-25T02:19:17ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-09-01659m1026m102610.1107/S1600536809030128Diaquabis(1,10-phenanthroline)magnesium dichromate(VI) 1,10-phenanthroline disolvateHai-Xing LiuGui-Ying DongZhi-Hong MaGuang-Hua CuiIn the title compound, [Mg(C12H8N2)2(H2O)2][Cr2O7]·2C12H8N2, the cation and anion are situated on a twofold rotation axis. The MgII ion is coordinated by four N atoms from two 1,10-phenanthroline ligands and two O atoms from coordinated water molecules in a distorted octahedral geometry. Intermolecular O—H...N and O—H...O hydrogen bonds and π–π interactions between the aromatic rings [shortest centroid–centroid separation = 3.527 (2) Å] link the cations, anions and 1,10-phenanthroline solvent molecules into a hydrogen-bonded cluster. http://scripts.iucr.org/cgi-bin/paper?S1600536809030128
collection DOAJ
language English
format Article
sources DOAJ
author Hai-Xing Liu
Gui-Ying Dong
Zhi-Hong Ma
Guang-Hua Cui
spellingShingle Hai-Xing Liu
Gui-Ying Dong
Zhi-Hong Ma
Guang-Hua Cui
Diaquabis(1,10-phenanthroline)magnesium dichromate(VI) 1,10-phenanthroline disolvate
Acta Crystallographica Section E
author_facet Hai-Xing Liu
Gui-Ying Dong
Zhi-Hong Ma
Guang-Hua Cui
author_sort Hai-Xing Liu
title Diaquabis(1,10-phenanthroline)magnesium dichromate(VI) 1,10-phenanthroline disolvate
title_short Diaquabis(1,10-phenanthroline)magnesium dichromate(VI) 1,10-phenanthroline disolvate
title_full Diaquabis(1,10-phenanthroline)magnesium dichromate(VI) 1,10-phenanthroline disolvate
title_fullStr Diaquabis(1,10-phenanthroline)magnesium dichromate(VI) 1,10-phenanthroline disolvate
title_full_unstemmed Diaquabis(1,10-phenanthroline)magnesium dichromate(VI) 1,10-phenanthroline disolvate
title_sort diaquabis(1,10-phenanthroline)magnesium dichromate(vi) 1,10-phenanthroline disolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-09-01
description In the title compound, [Mg(C12H8N2)2(H2O)2][Cr2O7]·2C12H8N2, the cation and anion are situated on a twofold rotation axis. The MgII ion is coordinated by four N atoms from two 1,10-phenanthroline ligands and two O atoms from coordinated water molecules in a distorted octahedral geometry. Intermolecular O—H...N and O—H...O hydrogen bonds and π–π interactions between the aromatic rings [shortest centroid–centroid separation = 3.527 (2) Å] link the cations, anions and 1,10-phenanthroline solvent molecules into a hydrogen-bonded cluster.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809030128
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AT guiyingdong diaquabis110phenanthrolinemagnesiumdichromatevi110phenanthrolinedisolvate
AT zhihongma diaquabis110phenanthrolinemagnesiumdichromatevi110phenanthrolinedisolvate
AT guanghuacui diaquabis110phenanthrolinemagnesiumdichromatevi110phenanthrolinedisolvate
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