Conjugated nitrosoalkenes as Michael acceptors in carbon–carbon bond forming reactions: a review and perspective

Despite of their chemical instability and high reactivity, conjugated nitrosoalkenes are useful intermediates in target-oriented organic synthesis. The present review deals with carbon–carbon bond forming reactions involving Michael addition to α-nitrosoalkenes with a particular focus on recent deve...

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Main Authors: Yaroslav D. Boyko, Valentin S. Dorokhov, Alexey Yu. Sukhorukov, Sema L. Ioffe
Format: Article
Language:English
Published: Beilstein-Institut 2017-10-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.13.220
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spelling doaj-7de863303bc5433fa7c5f1e3fe2c09e62021-02-02T08:19:11ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972017-10-011312214223410.3762/bjoc.13.2201860-5397-13-220Conjugated nitrosoalkenes as Michael acceptors in carbon–carbon bond forming reactions: a review and perspectiveYaroslav D. Boyko0Valentin S. Dorokhov1Alexey Yu. Sukhorukov2Sema L. Ioffe3N. D. Zelinsky Institute of Organic Chemistry, 119991, Leninsky prospect, 47, Moscow, RussiaN. D. Zelinsky Institute of Organic Chemistry, 119991, Leninsky prospect, 47, Moscow, RussiaN. D. Zelinsky Institute of Organic Chemistry, 119991, Leninsky prospect, 47, Moscow, RussiaN. D. Zelinsky Institute of Organic Chemistry, 119991, Leninsky prospect, 47, Moscow, RussiaDespite of their chemical instability and high reactivity, conjugated nitrosoalkenes are useful intermediates in target-oriented organic synthesis. The present review deals with carbon–carbon bond forming reactions involving Michael addition to α-nitrosoalkenes with a particular focus on recent developments in this methodology and its use in total synthesis.https://doi.org/10.3762/bjoc.13.220carbon–carbon bond formationMichael additionnitrosoalkenesoximestotal synthesis
collection DOAJ
language English
format Article
sources DOAJ
author Yaroslav D. Boyko
Valentin S. Dorokhov
Alexey Yu. Sukhorukov
Sema L. Ioffe
spellingShingle Yaroslav D. Boyko
Valentin S. Dorokhov
Alexey Yu. Sukhorukov
Sema L. Ioffe
Conjugated nitrosoalkenes as Michael acceptors in carbon–carbon bond forming reactions: a review and perspective
Beilstein Journal of Organic Chemistry
carbon–carbon bond formation
Michael addition
nitrosoalkenes
oximes
total synthesis
author_facet Yaroslav D. Boyko
Valentin S. Dorokhov
Alexey Yu. Sukhorukov
Sema L. Ioffe
author_sort Yaroslav D. Boyko
title Conjugated nitrosoalkenes as Michael acceptors in carbon–carbon bond forming reactions: a review and perspective
title_short Conjugated nitrosoalkenes as Michael acceptors in carbon–carbon bond forming reactions: a review and perspective
title_full Conjugated nitrosoalkenes as Michael acceptors in carbon–carbon bond forming reactions: a review and perspective
title_fullStr Conjugated nitrosoalkenes as Michael acceptors in carbon–carbon bond forming reactions: a review and perspective
title_full_unstemmed Conjugated nitrosoalkenes as Michael acceptors in carbon–carbon bond forming reactions: a review and perspective
title_sort conjugated nitrosoalkenes as michael acceptors in carbon–carbon bond forming reactions: a review and perspective
publisher Beilstein-Institut
series Beilstein Journal of Organic Chemistry
issn 1860-5397
publishDate 2017-10-01
description Despite of their chemical instability and high reactivity, conjugated nitrosoalkenes are useful intermediates in target-oriented organic synthesis. The present review deals with carbon–carbon bond forming reactions involving Michael addition to α-nitrosoalkenes with a particular focus on recent developments in this methodology and its use in total synthesis.
topic carbon–carbon bond formation
Michael addition
nitrosoalkenes
oximes
total synthesis
url https://doi.org/10.3762/bjoc.13.220
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AT alexeyyusukhorukov conjugatednitrosoalkenesasmichaelacceptorsincarboncarbonbondformingreactionsareviewandperspective
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