Diaqua(1,4,8,11-tetraazacyclotetradecane-κ4N1,N4,N8,N11)copper(II) bis(2,3,4,5,6-pentafluorobenzoate) dihydrate

Diaqua(1,4,8,11-tetraazacyclotetradecane-κ4N1,N4,N8,N11)copper(II) bis(2,3,4,5,6-pentafluorobenzoate) dihydrate

The CuII atom in the title salt, [Cu(C10H24N4)(H2O)2](C6F5CO2)2·2H2O, is chelated by the four N atoms of the 1,4,8,11-tetraazacyclotetradecane (cyclam) ligand and is coordinated by two water molecules in a Jahn–Teller-type tetragonally distorted octahedral geometry. The Cu...

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Main Authors: Nur Syamimi Ahmad Tajidi, Norbani Abdullah, Zainudin Arifin, Kong Wai Tan, Seik Weng Ng
Format: Article
Language:English
Published: International Union of Crystallography 2010-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810025705
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spelling doaj-7dc38273862a44568122f7d8c5485c852020-11-25T01:05:18ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-08-01668m889m88910.1107/S1600536810025705Diaqua(1,4,8,11-tetraazacyclotetradecane-κ4N1,N4,N8,N11)copper(II) bis(2,3,4,5,6-pentafluorobenzoate) dihydrateNur Syamimi Ahmad TajidiNorbani AbdullahZainudin ArifinKong Wai TanSeik Weng NgThe CuII atom in the title salt, [Cu(C10H24N4)(H2O)2](C6F5CO2)2·2H2O, is chelated by the four N atoms of the 1,4,8,11-tetraazacyclotetradecane (cyclam) ligand and is coordinated by two water molecules in a Jahn–Teller-type tetragonally distorted octahedral geometry. The CuII atom lies on a center of inversion. The cations, anions and uncoordinated water molecules are linked by N—H...O and O—H...O hydrogen bonds, forming a layer structure parallel to (001). http://scripts.iucr.org/cgi-bin/paper?S1600536810025705
collection DOAJ
language English
format Article
sources DOAJ
author Nur Syamimi Ahmad Tajidi
Norbani Abdullah
Zainudin Arifin
Kong Wai Tan
Seik Weng Ng
spellingShingle Nur Syamimi Ahmad Tajidi
Norbani Abdullah
Zainudin Arifin
Kong Wai Tan
Seik Weng Ng
Diaqua(1,4,8,11-tetraazacyclotetradecane-κ4N1,N4,N8,N11)copper(II) bis(2,3,4,5,6-pentafluorobenzoate) dihydrate
Acta Crystallographica Section E
author_facet Nur Syamimi Ahmad Tajidi
Norbani Abdullah
Zainudin Arifin
Kong Wai Tan
Seik Weng Ng
author_sort Nur Syamimi Ahmad Tajidi
title Diaqua(1,4,8,11-tetraazacyclotetradecane-κ4N1,N4,N8,N11)copper(II) bis(2,3,4,5,6-pentafluorobenzoate) dihydrate
title_short Diaqua(1,4,8,11-tetraazacyclotetradecane-κ4N1,N4,N8,N11)copper(II) bis(2,3,4,5,6-pentafluorobenzoate) dihydrate
title_full Diaqua(1,4,8,11-tetraazacyclotetradecane-κ4N1,N4,N8,N11)copper(II) bis(2,3,4,5,6-pentafluorobenzoate) dihydrate
title_fullStr Diaqua(1,4,8,11-tetraazacyclotetradecane-κ4N1,N4,N8,N11)copper(II) bis(2,3,4,5,6-pentafluorobenzoate) dihydrate
title_full_unstemmed Diaqua(1,4,8,11-tetraazacyclotetradecane-κ4N1,N4,N8,N11)copper(II) bis(2,3,4,5,6-pentafluorobenzoate) dihydrate
title_sort diaqua(1,4,8,11-tetraazacyclotetradecane-κ4n1,n4,n8,n11)copper(ii) bis(2,3,4,5,6-pentafluorobenzoate) dihydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-08-01
description The CuII atom in the title salt, [Cu(C10H24N4)(H2O)2](C6F5CO2)2·2H2O, is chelated by the four N atoms of the 1,4,8,11-tetraazacyclotetradecane (cyclam) ligand and is coordinated by two water molecules in a Jahn–Teller-type tetragonally distorted octahedral geometry. The CuII atom lies on a center of inversion. The cations, anions and uncoordinated water molecules are linked by N—H...O and O—H...O hydrogen bonds, forming a layer structure parallel to (001).
url http://scripts.iucr.org/cgi-bin/paper?S1600536810025705
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