Correlation between High Temperature Deformation and β Relaxation in LaCe-Based Metallic Glass

High-temperature deformation around the glass transition temperature T<sub>g</sub> and the dynamic mechanical behavior of La<sub>30</sub>Ce<sub>30</sub>Al<sub>15</sub>Co<sub>25</sub> metallic glass were investigated. According to dynamic me...

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Bibliographic Details
Main Authors: Yinghong Chen, Jichao Qiao
Format: Article
Language:English
Published: MDPI AG 2020-02-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/13/4/833
Description
Summary:High-temperature deformation around the glass transition temperature T<sub>g</sub> and the dynamic mechanical behavior of La<sub>30</sub>Ce<sub>30</sub>Al<sub>15</sub>Co<sub>25</sub> metallic glass were investigated. According to dynamic mechanical analysis (DMA) results, La<sub>30</sub>Ce<sub>30</sub>Al<sub>15</sub>Co<sub>25</sub> metallic glass exhibits a pronounced slow &#946; relaxation process. In parallel, strain-rate jump experiments around the glass transition temperature were performed in a wide range of strain rate ranges. The apparent viscosity shows a strong dependence on temperature and strain rate, which reflects the transition from non-Newtonian to Newtonian flow. At low strain or high temperature, a transition was observed from a non-Newtonian viscous flow to Newtonian viscous flow. It was found that the activation volume during plastic deformation of La<sub>30</sub>Ce<sub>30</sub>Al<sub>15</sub>Co<sub>25</sub> metallic glass is higher than that of other metallic glasses. Higher values of activation volume in La<sub>30</sub>Ce<sub>30</sub>Al<sub>15</sub>Co<sub>25</sub> metallic glass may be attributed to existence of a pronounced slow &#946; relaxation. It is reasonable to conclude that slow &#946; relaxation in La<sub>30</sub>Ce<sub>30</sub>Al<sub>15</sub>Co<sub>25</sub> metallic glass corresponds to the &#8220;soft&#8221; regions (structural heterogeneities) in metallic glass.
ISSN:1996-1944