Access to stereodefined (Z)-allylsilanes and (Z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenes
Controlling selectivity in the hydrosilylation of allenes poses serious challenges in terms of product stereochemistry. Here the authors show that the title reaction proceeds with excellent (Z)-selectivity by use of a cobalt catalyst in the presence of phosphine-based ligands.
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| Format: | Article |
| Language: | English |
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Nature Publishing Group
2017-12-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-017-02382-7 |
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doaj-7d9acfa72b1f4b9d96b8664f966346ef2021-05-11T07:02:30ZengNature Publishing GroupNature Communications2041-17232017-12-01811910.1038/s41467-017-02382-7Access to stereodefined (Z)-allylsilanes and (Z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenesChao Wang0Wei Jie Teo1Shaozhong Ge2Department of Chemistry, National University of SingaporeDepartment of Chemistry, National University of SingaporeDepartment of Chemistry, National University of SingaporeControlling selectivity in the hydrosilylation of allenes poses serious challenges in terms of product stereochemistry. Here the authors show that the title reaction proceeds with excellent (Z)-selectivity by use of a cobalt catalyst in the presence of phosphine-based ligands.https://doi.org/10.1038/s41467-017-02382-7 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Chao Wang Wei Jie Teo Shaozhong Ge |
| spellingShingle |
Chao Wang Wei Jie Teo Shaozhong Ge Access to stereodefined (Z)-allylsilanes and (Z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenes Nature Communications |
| author_facet |
Chao Wang Wei Jie Teo Shaozhong Ge |
| author_sort |
Chao Wang |
| title |
Access to stereodefined (Z)-allylsilanes and (Z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenes |
| title_short |
Access to stereodefined (Z)-allylsilanes and (Z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenes |
| title_full |
Access to stereodefined (Z)-allylsilanes and (Z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenes |
| title_fullStr |
Access to stereodefined (Z)-allylsilanes and (Z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenes |
| title_full_unstemmed |
Access to stereodefined (Z)-allylsilanes and (Z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenes |
| title_sort |
access to stereodefined (z)-allylsilanes and (z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenes |
| publisher |
Nature Publishing Group |
| series |
Nature Communications |
| issn |
2041-1723 |
| publishDate |
2017-12-01 |
| description |
Controlling selectivity in the hydrosilylation of allenes poses serious challenges in terms of product stereochemistry. Here the authors show that the title reaction proceeds with excellent (Z)-selectivity by use of a cobalt catalyst in the presence of phosphine-based ligands. |
| url |
https://doi.org/10.1038/s41467-017-02382-7 |
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