catena-Poly[[[tetrakis(cyanido-κC)tungstate(IV)]-di-μ-cyanido-κ4C:N-bis[diaqua(2,2′-bipyridyl-κ2N,N′)manganese(II)]-di-μ-cyanido-κ4N:C] hexahydrate]

catena-Poly[[[tetrakis(cyanido-κC)tungstate(IV)]-di-μ-cyanido-κ4C:N-bis[diaqua(2,2′-bipyridyl-κ2N,N′)manganese(II)]-di-μ-cyanido-κ4N:C] hexahydrate]

The polymeric title compound, {[MnII2WIV(CN)8(C10H8N2)2(H2O)4]·6H2O}n, has a one-dimensional cyanide-bridged MnII–WIV bimetallic assembly. The coordination geometry of the WIV atom is eight-coordinate square-antiprismatic and that of each of the MnII atoms is six-coordinat...

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Main Authors: Noriaki Ozaki, Ryo Yamada, Koji Nakabayashi, Shin-ichi Ohkoshi
Format: Article
Language:English
Published: International Union of Crystallography 2011-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811012451
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spelling doaj-7d915cfc7d884518be0e66de19b5ddab2020-11-25T00:22:23ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-06-01676m702m70310.1107/S1600536811012451catena-Poly[[[tetrakis(cyanido-κC)tungstate(IV)]-di-μ-cyanido-κ4C:N-bis[diaqua(2,2′-bipyridyl-κ2N,N′)manganese(II)]-di-μ-cyanido-κ4N:C] hexahydrate]Noriaki OzakiRyo YamadaKoji NakabayashiShin-ichi OhkoshiThe polymeric title compound, {[MnII2WIV(CN)8(C10H8N2)2(H2O)4]·6H2O}n, has a one-dimensional cyanide-bridged MnII–WIV bimetallic assembly. The coordination geometry of the WIV atom is eight-coordinate square-antiprismatic and that of each of the MnII atoms is six-coordinate distorted octahedral. Two pairs of CN ligands of W(CN)8 are bridged to two MnII atoms, the remaining CN ligands being terminal. Each MnII atom is additionally coordinated by a bidentate 2,2′-bipyridyl ligand and two water molecules. The crystal structure is stabilized by O—H...O and O—H...N hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536811012451
collection DOAJ
language English
format Article
sources DOAJ
author Noriaki Ozaki
Ryo Yamada
Koji Nakabayashi
Shin-ichi Ohkoshi
spellingShingle Noriaki Ozaki
Ryo Yamada
Koji Nakabayashi
Shin-ichi Ohkoshi
catena-Poly[[[tetrakis(cyanido-κC)tungstate(IV)]-di-μ-cyanido-κ4C:N-bis[diaqua(2,2′-bipyridyl-κ2N,N′)manganese(II)]-di-μ-cyanido-κ4N:C] hexahydrate]
Acta Crystallographica Section E
author_facet Noriaki Ozaki
Ryo Yamada
Koji Nakabayashi
Shin-ichi Ohkoshi
author_sort Noriaki Ozaki
title catena-Poly[[[tetrakis(cyanido-κC)tungstate(IV)]-di-μ-cyanido-κ4C:N-bis[diaqua(2,2′-bipyridyl-κ2N,N′)manganese(II)]-di-μ-cyanido-κ4N:C] hexahydrate]
title_short catena-Poly[[[tetrakis(cyanido-κC)tungstate(IV)]-di-μ-cyanido-κ4C:N-bis[diaqua(2,2′-bipyridyl-κ2N,N′)manganese(II)]-di-μ-cyanido-κ4N:C] hexahydrate]
title_full catena-Poly[[[tetrakis(cyanido-κC)tungstate(IV)]-di-μ-cyanido-κ4C:N-bis[diaqua(2,2′-bipyridyl-κ2N,N′)manganese(II)]-di-μ-cyanido-κ4N:C] hexahydrate]
title_fullStr catena-Poly[[[tetrakis(cyanido-κC)tungstate(IV)]-di-μ-cyanido-κ4C:N-bis[diaqua(2,2′-bipyridyl-κ2N,N′)manganese(II)]-di-μ-cyanido-κ4N:C] hexahydrate]
title_full_unstemmed catena-Poly[[[tetrakis(cyanido-κC)tungstate(IV)]-di-μ-cyanido-κ4C:N-bis[diaqua(2,2′-bipyridyl-κ2N,N′)manganese(II)]-di-μ-cyanido-κ4N:C] hexahydrate]
title_sort catena-poly[[[tetrakis(cyanido-κc)tungstate(iv)]-di-μ-cyanido-κ4c:n-bis[diaqua(2,2′-bipyridyl-κ2n,n′)manganese(ii)]-di-μ-cyanido-κ4n:c] hexahydrate]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-06-01
description The polymeric title compound, {[MnII2WIV(CN)8(C10H8N2)2(H2O)4]·6H2O}n, has a one-dimensional cyanide-bridged MnII–WIV bimetallic assembly. The coordination geometry of the WIV atom is eight-coordinate square-antiprismatic and that of each of the MnII atoms is six-coordinate distorted octahedral. Two pairs of CN ligands of W(CN)8 are bridged to two MnII atoms, the remaining CN ligands being terminal. Each MnII atom is additionally coordinated by a bidentate 2,2′-bipyridyl ligand and two water molecules. The crystal structure is stabilized by O—H...O and O—H...N hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811012451
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