Influence of percentages of ethanol alcohol on the acidity and basal of various imines derived from N-formylpipridine
Abstract<br /> The project describes the influence of five different percentages of ethanol in a range between (10-50)% in a mixture of ethanol-water on the acidity of thirteen imines as derived from N-formyl-pipyridine. These five percentages of ethanol-water mixtures have a clear influence o...
Main Authors: | , |
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Format: | Article |
Language: | Arabic |
Published: |
College of Education for Pure Sciences
2012-12-01
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Series: | مجلة التربية والعلم |
Subjects: | |
Online Access: | https://edusj.mosuljournals.com/article_70978_12b54b5e883cddb76ff26481218562ac.pdf |
Summary: | Abstract<br /> The project describes the influence of five different percentages of ethanol in a range between (10-50)% in a mixture of ethanol-water on the acidity of thirteen imines as derived from N-formyl-pipyridine. These five percentages of ethanol-water mixtures have a clear influence on the values of ionization constants pKa of imines. The plot between pKa versus the dielectric constant (D) of the medium for imines studied, shows a direct or an inverse linear plots. These variations in plots were interpreted in terms of solvation reaction for the ionization reactions of imines in the media stated previously. |
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ISSN: | 1812-125X 2664-2530 |