Tris(5,6-dimethyl-1,10-phenanthroline-κ2N,N′)iron(II) bis(tricyanomethanide)

Tris(5,6-dimethyl-1,10-phenanthroline-κ2N,N′)iron(II) bis(tricyanomethanide)

The title compound, [Fe(C14H12N2)3](C4N3)2, consists of one [Fe(dimephen)3]2+ complex cation (dimephen = 5,6-dimethyl-1,10-phenanthroline) and two uncoordinating tcm anions (tcm = tricyanomethanide). In the complex cation, the FeII atom is coordinated by six N atoms from three chelating dimephen lig...

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Main Authors: Lucia Váhovská, Ivan Potočňák
Format: Article
Language:English
Published: International Union of Crystallography 2012-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812046880
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spelling doaj-7d7a9c37884f47afb2dd6d6238310fa52020-11-24T21:26:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-12-016812m1524m152510.1107/S1600536812046880Tris(5,6-dimethyl-1,10-phenanthroline-κ2N,N′)iron(II) bis(tricyanomethanide)Lucia VáhovskáIvan PotočňákThe title compound, [Fe(C14H12N2)3](C4N3)2, consists of one [Fe(dimephen)3]2+ complex cation (dimephen = 5,6-dimethyl-1,10-phenanthroline) and two uncoordinating tcm anions (tcm = tricyanomethanide). In the complex cation, the FeII atom is coordinated by six N atoms from three chelating dimephen ligands at an average Fe—N distance of 1.963 (4) Å giving a distorted octahedral geometry. The crystal structure is stabilized by weak C—H...N hydrogen bonds and C[triple-bond]N...π interactions between planar [maximum deviations of 0.024 (3) and 0.015 (3) Å] tcm anions and pyridine rings of dimephen [N2...centroid = 3.531 (3) and 3.726 (3) Å; C[triple-bond]N...centroid = 96.4 (2) and 97.1 (2)°].http://scripts.iucr.org/cgi-bin/paper?S1600536812046880
collection DOAJ
language English
format Article
sources DOAJ
author Lucia Váhovská
Ivan Potočňák
spellingShingle Lucia Váhovská
Ivan Potočňák
Tris(5,6-dimethyl-1,10-phenanthroline-κ2N,N′)iron(II) bis(tricyanomethanide)
Acta Crystallographica Section E
author_facet Lucia Váhovská
Ivan Potočňák
author_sort Lucia Váhovská
title Tris(5,6-dimethyl-1,10-phenanthroline-κ2N,N′)iron(II) bis(tricyanomethanide)
title_short Tris(5,6-dimethyl-1,10-phenanthroline-κ2N,N′)iron(II) bis(tricyanomethanide)
title_full Tris(5,6-dimethyl-1,10-phenanthroline-κ2N,N′)iron(II) bis(tricyanomethanide)
title_fullStr Tris(5,6-dimethyl-1,10-phenanthroline-κ2N,N′)iron(II) bis(tricyanomethanide)
title_full_unstemmed Tris(5,6-dimethyl-1,10-phenanthroline-κ2N,N′)iron(II) bis(tricyanomethanide)
title_sort tris(5,6-dimethyl-1,10-phenanthroline-κ2n,n′)iron(ii) bis(tricyanomethanide)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-12-01
description The title compound, [Fe(C14H12N2)3](C4N3)2, consists of one [Fe(dimephen)3]2+ complex cation (dimephen = 5,6-dimethyl-1,10-phenanthroline) and two uncoordinating tcm anions (tcm = tricyanomethanide). In the complex cation, the FeII atom is coordinated by six N atoms from three chelating dimephen ligands at an average Fe—N distance of 1.963 (4) Å giving a distorted octahedral geometry. The crystal structure is stabilized by weak C—H...N hydrogen bonds and C[triple-bond]N...π interactions between planar [maximum deviations of 0.024 (3) and 0.015 (3) Å] tcm anions and pyridine rings of dimephen [N2...centroid = 3.531 (3) and 3.726 (3) Å; C[triple-bond]N...centroid = 96.4 (2) and 97.1 (2)°].
url http://scripts.iucr.org/cgi-bin/paper?S1600536812046880
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AT ivanpotoamp269amp328amp225k tris56dimethyl110phenanthrolineamp9542nnamp8242ironiibistricyanomethanide
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