3,3′-Dibenzyl-1,1′-[naphthalene-1,4-diylbis(methylene)]di(1H-imidazol-3-ium) bis(hexafluorophosphate)
In the title N-heterocyclic carbene compound, C32H30N42+·2PF6−, the mean plane of the naphthalene ring system makes dihedral angles of 79.15 (15) and 76.85 (16) with the imidazole rings and 56.15 (19) and 80.56 (16)&a...
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International Union of Crystallography
2011-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811032132 |
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doaj-7d4203499e0b4cb487e31e9f1ed8a58b2020-11-24T20:56:10ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-09-01679o2343o234310.1107/S16005368110321323,3′-Dibenzyl-1,1′-[naphthalene-1,4-diylbis(methylene)]di(1H-imidazol-3-ium) bis(hexafluorophosphate)Chang-Lu LiuKun HuangIn the title N-heterocyclic carbene compound, C32H30N42+·2PF6−, the mean plane of the naphthalene ring system makes dihedral angles of 79.15 (15) and 76.85 (16) with the imidazole rings and 56.15 (19) and 80.56 (16)° with the benzene rings. An intramolecular C—H...N hydrogen bond occurs. The crystal structure is stabilized by C—H...F interactions. In addition, π–π interactions [centroid–centroid distances = 3.848 (1) and 3.574 (3) Å] are observed. The nine equatorial F atoms in the two PF6− anions were disordered over two positions with occupancy ratios of 0.545 (10):0.455 (10) and 0.793 (11):0.207 (11) in the two anions.http://scripts.iucr.org/cgi-bin/paper?S1600536811032132 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Chang-Lu Liu Kun Huang |
| spellingShingle |
Chang-Lu Liu Kun Huang 3,3′-Dibenzyl-1,1′-[naphthalene-1,4-diylbis(methylene)]di(1H-imidazol-3-ium) bis(hexafluorophosphate) Acta Crystallographica Section E |
| author_facet |
Chang-Lu Liu Kun Huang |
| author_sort |
Chang-Lu Liu |
| title |
3,3′-Dibenzyl-1,1′-[naphthalene-1,4-diylbis(methylene)]di(1H-imidazol-3-ium) bis(hexafluorophosphate) |
| title_short |
3,3′-Dibenzyl-1,1′-[naphthalene-1,4-diylbis(methylene)]di(1H-imidazol-3-ium) bis(hexafluorophosphate) |
| title_full |
3,3′-Dibenzyl-1,1′-[naphthalene-1,4-diylbis(methylene)]di(1H-imidazol-3-ium) bis(hexafluorophosphate) |
| title_fullStr |
3,3′-Dibenzyl-1,1′-[naphthalene-1,4-diylbis(methylene)]di(1H-imidazol-3-ium) bis(hexafluorophosphate) |
| title_full_unstemmed |
3,3′-Dibenzyl-1,1′-[naphthalene-1,4-diylbis(methylene)]di(1H-imidazol-3-ium) bis(hexafluorophosphate) |
| title_sort |
3,3′-dibenzyl-1,1′-[naphthalene-1,4-diylbis(methylene)]di(1h-imidazol-3-ium) bis(hexafluorophosphate) |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2011-09-01 |
| description |
In the title N-heterocyclic carbene compound, C32H30N42+·2PF6−, the mean plane of the naphthalene ring system makes dihedral angles of 79.15 (15) and 76.85 (16) with the imidazole rings and 56.15 (19) and 80.56 (16)° with the benzene rings. An intramolecular C—H...N hydrogen bond occurs. The crystal structure is stabilized by C—H...F interactions. In addition, π–π interactions [centroid–centroid distances = 3.848 (1) and 3.574 (3) Å] are observed. The nine equatorial F atoms in the two PF6− anions were disordered over two positions with occupancy ratios of 0.545 (10):0.455 (10) and 0.793 (11):0.207 (11) in the two anions. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536811032132 |
| work_keys_str_mv |
AT changluliu 33amp8242dibenzyl11amp8242naphthalene14diylbismethylenedi1himidazol3iumbishexafluorophosphate AT kunhuang 33amp8242dibenzyl11amp8242naphthalene14diylbismethylenedi1himidazol3iumbishexafluorophosphate |
| _version_ |
1716790480121888768 |