rac-(S,S)-Bis(1-ferrocenylbut-3-enyl) ether

The title complex, [Fe2(C5H5)2(C18H20O)], formed by dehydration of 1-ferrocenylbut-3-en-1-ol, crystallizes as a racemic compound. The central C—O—C fragment, in which the C atoms are the chiral centers, is characterized by an angle of 116.26 (10)° at the O atom...

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Main Authors: Jian-Jun Wang, Si Chen, Jun Sun, Chun-Zheng Zhao, Hao-Jun Xie
Format: Article
Language:English
Published: International Union of Crystallography 2013-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812048064
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spelling doaj-7ce5ae16db9f46dfb567d9a2bf13796f2020-11-24T21:31:47ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-01-01691m16m1610.1107/S1600536812048064rac-(S,S)-Bis(1-ferrocenylbut-3-enyl) etherJian-Jun WangSi ChenJun SunChun-Zheng ZhaoHao-Jun XieThe title complex, [Fe2(C5H5)2(C18H20O)], formed by dehydration of 1-ferrocenylbut-3-en-1-ol, crystallizes as a racemic compound. The central C—O—C fragment, in which the C atoms are the chiral centers, is characterized by an angle of 116.26 (10)° at the O atom. One ferrocene group shows a staggered conformation whereas the other shows an eclipsed conformation.http://scripts.iucr.org/cgi-bin/paper?S1600536812048064
collection DOAJ
language English
format Article
sources DOAJ
author Jian-Jun Wang
Si Chen
Jun Sun
Chun-Zheng Zhao
Hao-Jun Xie
spellingShingle Jian-Jun Wang
Si Chen
Jun Sun
Chun-Zheng Zhao
Hao-Jun Xie
rac-(S,S)-Bis(1-ferrocenylbut-3-enyl) ether
Acta Crystallographica Section E
author_facet Jian-Jun Wang
Si Chen
Jun Sun
Chun-Zheng Zhao
Hao-Jun Xie
author_sort Jian-Jun Wang
title rac-(S,S)-Bis(1-ferrocenylbut-3-enyl) ether
title_short rac-(S,S)-Bis(1-ferrocenylbut-3-enyl) ether
title_full rac-(S,S)-Bis(1-ferrocenylbut-3-enyl) ether
title_fullStr rac-(S,S)-Bis(1-ferrocenylbut-3-enyl) ether
title_full_unstemmed rac-(S,S)-Bis(1-ferrocenylbut-3-enyl) ether
title_sort rac-(s,s)-bis(1-ferrocenylbut-3-enyl) ether
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2013-01-01
description The title complex, [Fe2(C5H5)2(C18H20O)], formed by dehydration of 1-ferrocenylbut-3-en-1-ol, crystallizes as a racemic compound. The central C—O—C fragment, in which the C atoms are the chiral centers, is characterized by an angle of 116.26 (10)° at the O atom. One ferrocene group shows a staggered conformation whereas the other shows an eclipsed conformation.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812048064
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