Electrical Properties of Composite Materials with Electric Field-Assisted Alignment of Nanocarbon Fillers

• Main Authors: Olena Yakovenko, Ludmila Matzui, Ganna Danylova, Victor Zadorozhnii, Ludmila Vovchenko, Yulia Perets, Oleksandra Lazarenko
• Format: Article
• Language: English
• Published: SpringerOpen 2017-07-01
• Series: Nanoscale Research Letters
• Subjects: Composites; Carbon nanotubes; Graphite nanoplatelets; Electric field-induced alignment; Depolarization factor; Electric conductivity
• Online Access: http://link.springer.com/article/10.1186/s11671-017-2244-0
• ISSN: 1931-7573; 1556-276X

Abstract The article reports about electric field-induced alignment of the carbon nanoparticles embedded in epoxy matrix. Optical microscopy was performed to consider the effect of the electric field magnitude and configuration, filler morphology, and aspect ratio on alignment process. Characteristic time of aligned network formation was compared with modeling predictions. Carbon nanotube and graphite nanoplatelet rotation time was estimated using an analytical model based on effective medium approach. Different depolarization factor was applied according to the geometries of the particle and electric field. Solid nanocomposites were fabricated by using AC electric field. We have investigated concentration dependence of electrical conductivity of graphite nanoplatelets/epoxy composites using two-probe technique. It was established that the electrical properties of composites with random and aligned filler distribution are differ by conductivity value at certain filler content and distinguish by a form of concentration dependence of conductivity for fillers with different morphology. These differences were explained in terms of the dynamic percolation and formation of various conductive networks: chained in case of graphite nanoplatelets and crossed framework in case of carbon nanotubes filler.