Nitrogen Configuration of Polybenzoxazine Carbide

Carbon materials should have specific centers for its functionalities. In this study, the specific centers of polybenzoxazine carbides were studied for the first time. Three classical benzoxazine monomers were chose as the object. The transformation of nitrogen configuration of polybenzoxazines carb...

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Main Authors:	Zhang Huachuan, Gu Wu, Zhu Rongqi, Ran Qichao, Gu Yi
Format:	Article
Language:	English
Published:	De Gruyter 2015-05-01
Series:	High Temperature Materials and Processes
Subjects:	polybenzoxazine carbides nitrogen configuration pyrolysis-gas chromatography-mass spectrometry x-ray photoelectron spectroscopy 61.48.gh
Online Access:	https://doi.org/10.1515/htmp-2014-0037

id	doaj-7ca6d57a906c4afb9e14c62bfc28f7e5
record_format	Article
spelling	doaj-7ca6d57a906c4afb9e14c62bfc28f7e52021-09-06T19:19:53ZengDe GruyterHigh Temperature Materials and Processes0334-64552191-03242015-05-0134324525010.1515/htmp-2014-0037Nitrogen Configuration of Polybenzoxazine CarbideZhang Huachuan0Gu Wu1Zhu Rongqi2Ran Qichao3Gu Yi4State Key Laboratory of Polymer Materials Engineering, College of Polymer Science and Engineering, Sichuan University, Chengdu 610065, ChinaState Key Laboratory of Polymer Materials Engineering, College of Polymer Science and Engineering, Sichuan University, Chengdu 610065, ChinaState Key Laboratory of Polymer Materials Engineering, College of Polymer Science and Engineering, Sichuan University, Chengdu 610065, ChinaState Key Laboratory of Polymer Materials Engineering, College of Polymer Science and Engineering, Sichuan University, Chengdu 610065, ChinaState Key Laboratory of Polymer Materials Engineering, College of Polymer Science and Engineering, Sichuan University, Chengdu 610065, ChinaCarbon materials should have specific centers for its functionalities. In this study, the specific centers of polybenzoxazine carbides were studied for the first time. Three classical benzoxazine monomers were chose as the object. The transformation of nitrogen configuration of polybenzoxazines carbides was characterized via pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS) and X-ray photoelectron spectroscopy (XPS). The results showed that the tertiary amine nitrogen converted to pyridinic nitrogen and pyrrolic nitrogen incorporated in graphene residuals during the carbonization, which were the specific centers for the functionality.https://doi.org/10.1515/htmp-2014-0037polybenzoxazinecarbidesnitrogen configurationpyrolysis-gas chromatography-mass spectrometryx-ray photoelectron spectroscopy61.48.gh
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Zhang Huachuan Gu Wu Zhu Rongqi Ran Qichao Gu Yi
spellingShingle	Zhang Huachuan Gu Wu Zhu Rongqi Ran Qichao Gu Yi Nitrogen Configuration of Polybenzoxazine Carbide High Temperature Materials and Processes polybenzoxazine carbides nitrogen configuration pyrolysis-gas chromatography-mass spectrometry x-ray photoelectron spectroscopy 61.48.gh
author_facet	Zhang Huachuan Gu Wu Zhu Rongqi Ran Qichao Gu Yi
author_sort	Zhang Huachuan
title	Nitrogen Configuration of Polybenzoxazine Carbide
title_short	Nitrogen Configuration of Polybenzoxazine Carbide
title_full	Nitrogen Configuration of Polybenzoxazine Carbide
title_fullStr	Nitrogen Configuration of Polybenzoxazine Carbide
title_full_unstemmed	Nitrogen Configuration of Polybenzoxazine Carbide
title_sort	nitrogen configuration of polybenzoxazine carbide
publisher	De Gruyter
series	High Temperature Materials and Processes
issn	0334-6455 2191-0324
publishDate	2015-05-01
description	Carbon materials should have specific centers for its functionalities. In this study, the specific centers of polybenzoxazine carbides were studied for the first time. Three classical benzoxazine monomers were chose as the object. The transformation of nitrogen configuration of polybenzoxazines carbides was characterized via pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS) and X-ray photoelectron spectroscopy (XPS). The results showed that the tertiary amine nitrogen converted to pyridinic nitrogen and pyrrolic nitrogen incorporated in graphene residuals during the carbonization, which were the specific centers for the functionality.
topic	polybenzoxazine carbides nitrogen configuration pyrolysis-gas chromatography-mass spectrometry x-ray photoelectron spectroscopy 61.48.gh
url	https://doi.org/10.1515/htmp-2014-0037
work_keys_str_mv	AT zhanghuachuan nitrogenconfigurationofpolybenzoxazinecarbide AT guwu nitrogenconfigurationofpolybenzoxazinecarbide AT zhurongqi nitrogenconfigurationofpolybenzoxazinecarbide AT ranqichao nitrogenconfigurationofpolybenzoxazinecarbide AT guyi nitrogenconfigurationofpolybenzoxazinecarbide
_version_	1717777634044149760

Nitrogen Configuration of Polybenzoxazine Carbide

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