4-(Dimethylamino)pyridinium dibromidotriphenylstannate(IV)

The anion in the title salt, (C7H11N2)[SnBr2(C6H5)3], lies on a twofold rotation axis that passes through the metal atom as well as the Cipso—Cpara atoms of one of the aromatic rings. The metal center is five-coordinate in a trans-Br2SnC3 trigonal bipyramidal geometry. The cation is disord...

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Bibliographic Details
Main Authors: Seik Weng Ng, Kong Mun Lo, Ilyana Norhafiza
Format: Article
Language:English
Published: International Union of Crystallography 2008-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808011094
Description
Summary:The anion in the title salt, (C7H11N2)[SnBr2(C6H5)3], lies on a twofold rotation axis that passes through the metal atom as well as the Cipso—Cpara atoms of one of the aromatic rings. The metal center is five-coordinate in a trans-Br2SnC3 trigonal bipyramidal geometry. The cation is disordered about a center of inversion.
ISSN:1600-5368