Effect of the Substitution of S for Se on the Optical Absorption Spectra of the Glassy Alloys Ag<sub>1.6</sub>Ga<sub>1.6</sub>Ge<sub>31.2</sub>S<sub>61.6-x</sub>Se<sub>x</sub>

<p>Optical absorption spectra of the glassy alloys Ag&lt;sub&gt;1.6&lt;/sub&gt;Ga&lt;sub&gt;1.6&lt;/sub&gt;Ge&lt;sub&gt;31.2&lt;/sub&gt;S&lt;sub&gt;61.6-x&lt;/sub&gt;Se&lt;sub&gt;x&lt;/sub&gt; in the range of 400-1...

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Main Authors: V. V. Halyan, A. H. Kevshyn, I. A. Ivashchenko, M. V. Shevchuk
Format: Article
Language:English
Published: Vasyl Stefanyk Precarpathian National University 2016-09-01
Series:Фізика і хімія твердого тіла
Online Access:http://journals.pu.if.ua/index.php/pcss/article/view/1436
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spelling doaj-7c39299d3b75404d9360db930156ebab2020-11-25T02:21:14ZengVasyl Stefanyk Precarpathian National UniversityФізика і хімія твердого тіла1729-44282309-85892016-09-0117334234510.15330/pcss.17.3.342-3451837Effect of the Substitution of S for Se on the Optical Absorption Spectra of the Glassy Alloys Ag<sub>1.6</sub>Ga<sub>1.6</sub>Ge<sub>31.2</sub>S<sub>61.6-x</sub>Se<sub>x</sub>V. V. Halyan0A. H. Kevshyn1I. A. Ivashchenko2M. V. Shevchuk3Східноєвропейський національний університет імені Лесі Українки.Східноєвропейський національний університет імені Лесі Українки.Східноєвропейський національний університет імені Лесі Українки.Луцький національний технічний.<p>Optical absorption spectra of the glassy alloys Ag&lt;sub&gt;1.6&lt;/sub&gt;Ga&lt;sub&gt;1.6&lt;/sub&gt;Ge&lt;sub&gt;31.2&lt;/sub&gt;S&lt;sub&gt;61.6-x&lt;/sub&gt;Se&lt;sub&gt;x&lt;/sub&gt; in the range of 400-1000 nm at 80 and 300 K have been investigated. It was revealed that with increasing of Se the width of the energy gap of the glasses decreases. In samples with x = 13.1, 19.7, 26.2, 32.8, 45.9, 52.5 at 80 K the photoluminescence was observed. It has the vague of peak and half-width emission band ΔE≈0,26-0,30 eV, which is characteristic for the recombination luminescence of the disordered systems. Peculiarities of the optical absorption spectra and photoluminescence are in good correlation with Mott's and Davis' model for localization energy states in the disordered systems.</p><p>Keywords: glassy alloys, optical absorption, photoluminescence.</p>http://journals.pu.if.ua/index.php/pcss/article/view/1436
collection DOAJ
language English
format Article
sources DOAJ
author V. V. Halyan
A. H. Kevshyn
I. A. Ivashchenko
M. V. Shevchuk
spellingShingle V. V. Halyan
A. H. Kevshyn
I. A. Ivashchenko
M. V. Shevchuk
Effect of the Substitution of S for Se on the Optical Absorption Spectra of the Glassy Alloys Ag<sub>1.6</sub>Ga<sub>1.6</sub>Ge<sub>31.2</sub>S<sub>61.6-x</sub>Se<sub>x</sub>
Фізика і хімія твердого тіла
author_facet V. V. Halyan
A. H. Kevshyn
I. A. Ivashchenko
M. V. Shevchuk
author_sort V. V. Halyan
title Effect of the Substitution of S for Se on the Optical Absorption Spectra of the Glassy Alloys Ag<sub>1.6</sub>Ga<sub>1.6</sub>Ge<sub>31.2</sub>S<sub>61.6-x</sub>Se<sub>x</sub>
title_short Effect of the Substitution of S for Se on the Optical Absorption Spectra of the Glassy Alloys Ag<sub>1.6</sub>Ga<sub>1.6</sub>Ge<sub>31.2</sub>S<sub>61.6-x</sub>Se<sub>x</sub>
title_full Effect of the Substitution of S for Se on the Optical Absorption Spectra of the Glassy Alloys Ag<sub>1.6</sub>Ga<sub>1.6</sub>Ge<sub>31.2</sub>S<sub>61.6-x</sub>Se<sub>x</sub>
title_fullStr Effect of the Substitution of S for Se on the Optical Absorption Spectra of the Glassy Alloys Ag<sub>1.6</sub>Ga<sub>1.6</sub>Ge<sub>31.2</sub>S<sub>61.6-x</sub>Se<sub>x</sub>
title_full_unstemmed Effect of the Substitution of S for Se on the Optical Absorption Spectra of the Glassy Alloys Ag<sub>1.6</sub>Ga<sub>1.6</sub>Ge<sub>31.2</sub>S<sub>61.6-x</sub>Se<sub>x</sub>
title_sort effect of the substitution of s for se on the optical absorption spectra of the glassy alloys ag<sub>1.6</sub>ga<sub>1.6</sub>ge<sub>31.2</sub>s<sub>61.6-x</sub>se<sub>x</sub>
publisher Vasyl Stefanyk Precarpathian National University
series Фізика і хімія твердого тіла
issn 1729-4428
2309-8589
publishDate 2016-09-01
description <p>Optical absorption spectra of the glassy alloys Ag&lt;sub&gt;1.6&lt;/sub&gt;Ga&lt;sub&gt;1.6&lt;/sub&gt;Ge&lt;sub&gt;31.2&lt;/sub&gt;S&lt;sub&gt;61.6-x&lt;/sub&gt;Se&lt;sub&gt;x&lt;/sub&gt; in the range of 400-1000 nm at 80 and 300 K have been investigated. It was revealed that with increasing of Se the width of the energy gap of the glasses decreases. In samples with x = 13.1, 19.7, 26.2, 32.8, 45.9, 52.5 at 80 K the photoluminescence was observed. It has the vague of peak and half-width emission band ΔE≈0,26-0,30 eV, which is characteristic for the recombination luminescence of the disordered systems. Peculiarities of the optical absorption spectra and photoluminescence are in good correlation with Mott's and Davis' model for localization energy states in the disordered systems.</p><p>Keywords: glassy alloys, optical absorption, photoluminescence.</p>
url http://journals.pu.if.ua/index.php/pcss/article/view/1436
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