rac-cis-5-Methyl-2,3-diphenyl-1,3-thiazolidin-4-one
In the racemic title compound, C16H15NOS, the thiazolidine ring adopts an envelope conformation, with the S atom as the flap. The dihedral angles between the heterocycle (all atoms) and pendant C– and N-bound benzene rings are 69.75 (14) and 56.56 (11)°, respectively; the aromatic rings are almost o...
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International Union of Crystallography
2017-11-01
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314617016625 |
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doaj-7c23f98d38dd4d7694557999159acf592020-11-24T23:42:19ZengInternational Union of CrystallographyIUCrData2414-31462017-11-01211x17166210.1107/S2414314617016625hb4181rac-cis-5-Methyl-2,3-diphenyl-1,3-thiazolidin-4-oneHemant P. Yennawar0John Tierney1Lee J. Silverberg2Department of Biochemistry and Molecular Biology, Pennsylvania State University, University Park, PA 16802, USAPennsylvania State University, Brandywine Campus, 312 Main Building, Brandywine, PA 19063, USAPennsylvania State University, Schuylkill Campus, 200 University Drive, Schuylkill Haven, PA 17972, USAIn the racemic title compound, C16H15NOS, the thiazolidine ring adopts an envelope conformation, with the S atom as the flap. The dihedral angles between the heterocycle (all atoms) and pendant C– and N-bound benzene rings are 69.75 (14) and 56.56 (11)°, respectively; the aromatic rings are almost orthogonal to each other, with a dihedral angle of 76.04 (14)° between them. In the crystal, molecules are linked by weak C—H...O hydrogen bonds to generate [101] chains, with alternating molecules being enantiomers. A weak C—H...π interaction is also observed.http://scripts.iucr.org/cgi-bin/paper?S2414314617016625crystal structurethiazolidineenvelope puckerC—H...O interactionsweak aromatic interactions |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Hemant P. Yennawar John Tierney Lee J. Silverberg |
| spellingShingle |
Hemant P. Yennawar John Tierney Lee J. Silverberg rac-cis-5-Methyl-2,3-diphenyl-1,3-thiazolidin-4-one IUCrData crystal structure thiazolidine envelope pucker C—H...O interactions weak aromatic interactions |
| author_facet |
Hemant P. Yennawar John Tierney Lee J. Silverberg |
| author_sort |
Hemant P. Yennawar |
| title |
rac-cis-5-Methyl-2,3-diphenyl-1,3-thiazolidin-4-one |
| title_short |
rac-cis-5-Methyl-2,3-diphenyl-1,3-thiazolidin-4-one |
| title_full |
rac-cis-5-Methyl-2,3-diphenyl-1,3-thiazolidin-4-one |
| title_fullStr |
rac-cis-5-Methyl-2,3-diphenyl-1,3-thiazolidin-4-one |
| title_full_unstemmed |
rac-cis-5-Methyl-2,3-diphenyl-1,3-thiazolidin-4-one |
| title_sort |
rac-cis-5-methyl-2,3-diphenyl-1,3-thiazolidin-4-one |
| publisher |
International Union of Crystallography |
| series |
IUCrData |
| issn |
2414-3146 |
| publishDate |
2017-11-01 |
| description |
In the racemic title compound, C16H15NOS, the thiazolidine ring adopts an envelope conformation, with the S atom as the flap. The dihedral angles between the heterocycle (all atoms) and pendant C– and N-bound benzene rings are 69.75 (14) and 56.56 (11)°, respectively; the aromatic rings are almost orthogonal to each other, with a dihedral angle of 76.04 (14)° between them. In the crystal, molecules are linked by weak C—H...O hydrogen bonds to generate [101] chains, with alternating molecules being enantiomers. A weak C—H...π interaction is also observed. |
| topic |
crystal structure thiazolidine envelope pucker C—H...O interactions weak aromatic interactions |
| url |
http://scripts.iucr.org/cgi-bin/paper?S2414314617016625 |
| work_keys_str_mv |
AT hemantpyennawar raccis5methyl23diphenyl13thiazolidin4one AT johntierney raccis5methyl23diphenyl13thiazolidin4one AT leejsilverberg raccis5methyl23diphenyl13thiazolidin4one |
| _version_ |
1725505061503631360 |