A Water Cluster Conduit in Crystal

The crystal structure of compound (1), [CuCl(phen)(H2NCH2COO)]∙4H2O, reveals an unusual hydrogen-bond water cluster aggregate T6(2)6(2). Four water molecules in (1) form an isolated water cluster, [(H2O)14]n, resembling a “phenanthro-[1,2]phenanthrene polymer structure shape” along the ac plane. The...

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Bibliographic Details
Main Authors:	Fangfang Jian, E Liu, Jiao Xu
Format:	Article
Language:	English
Published:	MDPI AG 2017-12-01
Series:	Molecules
Subjects:	glycine water cluster nanometer sized crystal hydrogen-bond
Online Access:	https://www.mdpi.com/1420-3049/22/12/2278

id	doaj-7c1c23023141485282534233c9ee7e71
record_format	Article
spelling	doaj-7c1c23023141485282534233c9ee7e712020-11-25T01:02:25ZengMDPI AGMolecules1420-30492017-12-012212227810.3390/molecules22122278molecules22122278A Water Cluster Conduit in CrystalFangfang Jian0E Liu1Jiao Xu2School of Chemical Engineering and Pharmaceutics, Henan University of Science and Technology, Luoyang 471023, ChinaSchool of Chemical Engineering and Pharmaceutics, Henan University of Science and Technology, Luoyang 471023, ChinaSchool of Chemical Engineering and Pharmaceutics, Henan University of Science and Technology, Luoyang 471023, ChinaThe crystal structure of compound (1), [CuCl(phen)(H2NCH2COO)]∙4H2O, reveals an unusual hydrogen-bond water cluster aggregate T6(2)6(2). Four water molecules in (1) form an isolated water cluster, [(H2O)14]n, resembling a “phenanthro-[1,2]phenanthrene polymer structure shape” along the ac plane. The two face-face parallel [(H2O)14]n planes are bridged by Cl atoms in [CuCl(phen) (H2NCH2COO)] with a strong O-H∙∙∙Cl hydrogen bond to form a water cluster conduit.https://www.mdpi.com/1420-3049/22/12/2278glycinewater clusternanometer sizedcrystalhydrogen-bond
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Fangfang Jian E Liu Jiao Xu
spellingShingle	Fangfang Jian E Liu Jiao Xu A Water Cluster Conduit in Crystal Molecules glycine water cluster nanometer sized crystal hydrogen-bond
author_facet	Fangfang Jian E Liu Jiao Xu
author_sort	Fangfang Jian
title	A Water Cluster Conduit in Crystal
title_short	A Water Cluster Conduit in Crystal
title_full	A Water Cluster Conduit in Crystal
title_fullStr	A Water Cluster Conduit in Crystal
title_full_unstemmed	A Water Cluster Conduit in Crystal
title_sort	water cluster conduit in crystal
publisher	MDPI AG
series	Molecules
issn	1420-3049
publishDate	2017-12-01
description	The crystal structure of compound (1), [CuCl(phen)(H2NCH2COO)]∙4H2O, reveals an unusual hydrogen-bond water cluster aggregate T6(2)6(2). Four water molecules in (1) form an isolated water cluster, [(H2O)14]n, resembling a “phenanthro-[1,2]phenanthrene polymer structure shape” along the ac plane. The two face-face parallel [(H2O)14]n planes are bridged by Cl atoms in [CuCl(phen) (H2NCH2COO)] with a strong O-H∙∙∙Cl hydrogen bond to form a water cluster conduit.
topic	glycine water cluster nanometer sized crystal hydrogen-bond
url	https://www.mdpi.com/1420-3049/22/12/2278
work_keys_str_mv	AT fangfangjian awaterclusterconduitincrystal AT eliu awaterclusterconduitincrystal AT jiaoxu awaterclusterconduitincrystal AT fangfangjian waterclusterconduitincrystal AT eliu waterclusterconduitincrystal AT jiaoxu waterclusterconduitincrystal
_version_	1725205129151381504

A Water Cluster Conduit in Crystal

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