catena-Poly[[[bis[4-(1H-1,3,7,8-tetraazacyclopenta[l]phenanthren-2-yl)phenol-κ2N7,N8]manganese(II)]-μ-naphthalene-1,4-dicarboxylato-κ2O1:O4] naphthalene-1,4-dicarboxylic acid hemisolvate monohydrate]

catena-Poly[[[bis[4-(1H-1,3,7,8-tetraazacyclopenta[l]phenanthren-2-yl)phenol-κ2N7,N8]manganese(II)]-μ-naphthalene-1,4-dicarboxylato-κ2O1:O4] naphthalene-1,4-dicarboxylic acid hemisolvate monohydrate]

The 1,4-dicarboxylate dianions in the title compound, [Mn(C12H6O4)(C19H12N4O)2]·0.5C12H8O4·H2O, bond to two 4-(1H-1,3,7,8-tetraazacyclopenta[l]phenanthren-2-yl)phenol-chelated Mn atoms to form a chain that features the metal atom in an octahedral coordination geometry. Adjacent cha...

Full description

Bibliographic Details
Main Authors: Seik Weng Ng, Mao-Liang Xu, Xiu-Ying Li, Heng-Da Li
Format: Article
Language:English
Published: International Union of Crystallography 2008-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053680801074X
id doaj-7bfb4f8118354ac186de9db192bf5937
record_format Article
spelling doaj-7bfb4f8118354ac186de9db192bf59372020-11-25T02:16:39ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-05-01645m701m70210.1107/S160053680801074Xcatena-Poly[[[bis[4-(1H-1,3,7,8-tetraazacyclopenta[l]phenanthren-2-yl)phenol-κ2N7,N8]manganese(II)]-μ-naphthalene-1,4-dicarboxylato-κ2O1:O4] naphthalene-1,4-dicarboxylic acid hemisolvate monohydrate]Seik Weng NgMao-Liang XuXiu-Ying LiHeng-Da LiThe 1,4-dicarboxylate dianions in the title compound, [Mn(C12H6O4)(C19H12N4O)2]·0.5C12H8O4·H2O, bond to two 4-(1H-1,3,7,8-tetraazacyclopenta[l]phenanthren-2-yl)phenol-chelated Mn atoms to form a chain that features the metal atom in an octahedral coordination geometry. Adjacent chains interact with the uncoordinated water molecules to form a three-dimensional network. The naphthalene-1,4-dicarboxylic acid solvent molecule, which is disordered about a centre of inversion, occupies the space within the network but is not bonded to the network. One NH group is disordered equally over two positions.http://scripts.iucr.org/cgi-bin/paper?S160053680801074X
collection DOAJ
language English
format Article
sources DOAJ
author Seik Weng Ng
Mao-Liang Xu
Xiu-Ying Li
Heng-Da Li
spellingShingle Seik Weng Ng
Mao-Liang Xu
Xiu-Ying Li
Heng-Da Li
catena-Poly[[[bis[4-(1H-1,3,7,8-tetraazacyclopenta[l]phenanthren-2-yl)phenol-κ2N7,N8]manganese(II)]-μ-naphthalene-1,4-dicarboxylato-κ2O1:O4] naphthalene-1,4-dicarboxylic acid hemisolvate monohydrate]
Acta Crystallographica Section E
author_facet Seik Weng Ng
Mao-Liang Xu
Xiu-Ying Li
Heng-Da Li
author_sort Seik Weng Ng
title catena-Poly[[[bis[4-(1H-1,3,7,8-tetraazacyclopenta[l]phenanthren-2-yl)phenol-κ2N7,N8]manganese(II)]-μ-naphthalene-1,4-dicarboxylato-κ2O1:O4] naphthalene-1,4-dicarboxylic acid hemisolvate monohydrate]
title_short catena-Poly[[[bis[4-(1H-1,3,7,8-tetraazacyclopenta[l]phenanthren-2-yl)phenol-κ2N7,N8]manganese(II)]-μ-naphthalene-1,4-dicarboxylato-κ2O1:O4] naphthalene-1,4-dicarboxylic acid hemisolvate monohydrate]
title_full catena-Poly[[[bis[4-(1H-1,3,7,8-tetraazacyclopenta[l]phenanthren-2-yl)phenol-κ2N7,N8]manganese(II)]-μ-naphthalene-1,4-dicarboxylato-κ2O1:O4] naphthalene-1,4-dicarboxylic acid hemisolvate monohydrate]
title_fullStr catena-Poly[[[bis[4-(1H-1,3,7,8-tetraazacyclopenta[l]phenanthren-2-yl)phenol-κ2N7,N8]manganese(II)]-μ-naphthalene-1,4-dicarboxylato-κ2O1:O4] naphthalene-1,4-dicarboxylic acid hemisolvate monohydrate]
title_full_unstemmed catena-Poly[[[bis[4-(1H-1,3,7,8-tetraazacyclopenta[l]phenanthren-2-yl)phenol-κ2N7,N8]manganese(II)]-μ-naphthalene-1,4-dicarboxylato-κ2O1:O4] naphthalene-1,4-dicarboxylic acid hemisolvate monohydrate]
title_sort catena-poly[[[bis[4-(1h-1,3,7,8-tetraazacyclopenta[l]phenanthren-2-yl)phenol-κ2n7,n8]manganese(ii)]-μ-naphthalene-1,4-dicarboxylato-κ2o1:o4] naphthalene-1,4-dicarboxylic acid hemisolvate monohydrate]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-05-01
description The 1,4-dicarboxylate dianions in the title compound, [Mn(C12H6O4)(C19H12N4O)2]·0.5C12H8O4·H2O, bond to two 4-(1H-1,3,7,8-tetraazacyclopenta[l]phenanthren-2-yl)phenol-chelated Mn atoms to form a chain that features the metal atom in an octahedral coordination geometry. Adjacent chains interact with the uncoordinated water molecules to form a three-dimensional network. The naphthalene-1,4-dicarboxylic acid solvent molecule, which is disordered about a centre of inversion, occupies the space within the network but is not bonded to the network. One NH group is disordered equally over two positions.
url http://scripts.iucr.org/cgi-bin/paper?S160053680801074X
work_keys_str_mv AT seikwengng catenapolybis41h1378tetraazacyclopentalphenanthren2ylphenol9542n7n8manganeseii956naphthalene14dicarboxylato9542o1o4naphthalene14dicarboxylicacidhemisolvatemonohydrate
AT maoliangxu catenapolybis41h1378tetraazacyclopentalphenanthren2ylphenol9542n7n8manganeseii956naphthalene14dicarboxylato9542o1o4naphthalene14dicarboxylicacidhemisolvatemonohydrate
AT xiuyingli catenapolybis41h1378tetraazacyclopentalphenanthren2ylphenol9542n7n8manganeseii956naphthalene14dicarboxylato9542o1o4naphthalene14dicarboxylicacidhemisolvatemonohydrate
AT hengdali catenapolybis41h1378tetraazacyclopentalphenanthren2ylphenol9542n7n8manganeseii956naphthalene14dicarboxylato9542o1o4naphthalene14dicarboxylicacidhemisolvatemonohydrate
_version_ 1724890041659949056

Similar Items