Rate and selectivity hysteresis during the carbon monoxide hydrogenation over promoted Co/MnOx catalysts
The question for the structure-reactivity relationship of cobalt-based catalysts for the carbon monoxide hydrogenation is as old as the reaction itself. Here the authors show kinetic hysteresis for a potassium-promoted cobalt-manganese oxide catalyst to be driven by the Co-Co2C phase transition.
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| Format: | Article |
| Language: | English |
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Nature Publishing Group
2019-09-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-019-11836-z |
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doaj-7bf032a5a699408cb0d8de527d3dc0c62021-05-11T12:19:38ZengNature Publishing GroupNature Communications2041-17232019-09-011011710.1038/s41467-019-11836-zRate and selectivity hysteresis during the carbon monoxide hydrogenation over promoted Co/MnOx catalystsYizhi Xiang0Libor Kovarik1Norbert Kruse2Voiland School of Chemical Engineering and Bioengineering, Washington State UniversityEnvironmental Molecular Science Laboratory, Pacific Northwest National LaboratoryVoiland School of Chemical Engineering and Bioengineering, Washington State UniversityThe question for the structure-reactivity relationship of cobalt-based catalysts for the carbon monoxide hydrogenation is as old as the reaction itself. Here the authors show kinetic hysteresis for a potassium-promoted cobalt-manganese oxide catalyst to be driven by the Co-Co2C phase transition.https://doi.org/10.1038/s41467-019-11836-z |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Yizhi Xiang Libor Kovarik Norbert Kruse |
| spellingShingle |
Yizhi Xiang Libor Kovarik Norbert Kruse Rate and selectivity hysteresis during the carbon monoxide hydrogenation over promoted Co/MnOx catalysts Nature Communications |
| author_facet |
Yizhi Xiang Libor Kovarik Norbert Kruse |
| author_sort |
Yizhi Xiang |
| title |
Rate and selectivity hysteresis during the carbon monoxide hydrogenation over promoted Co/MnOx catalysts |
| title_short |
Rate and selectivity hysteresis during the carbon monoxide hydrogenation over promoted Co/MnOx catalysts |
| title_full |
Rate and selectivity hysteresis during the carbon monoxide hydrogenation over promoted Co/MnOx catalysts |
| title_fullStr |
Rate and selectivity hysteresis during the carbon monoxide hydrogenation over promoted Co/MnOx catalysts |
| title_full_unstemmed |
Rate and selectivity hysteresis during the carbon monoxide hydrogenation over promoted Co/MnOx catalysts |
| title_sort |
rate and selectivity hysteresis during the carbon monoxide hydrogenation over promoted co/mnox catalysts |
| publisher |
Nature Publishing Group |
| series |
Nature Communications |
| issn |
2041-1723 |
| publishDate |
2019-09-01 |
| description |
The question for the structure-reactivity relationship of cobalt-based catalysts for the carbon monoxide hydrogenation is as old as the reaction itself. Here the authors show kinetic hysteresis for a potassium-promoted cobalt-manganese oxide catalyst to be driven by the Co-Co2C phase transition. |
| url |
https://doi.org/10.1038/s41467-019-11836-z |
| work_keys_str_mv |
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