Rate and selectivity hysteresis during the carbon monoxide hydrogenation over promoted Co/MnOx catalysts
The question for the structure-reactivity relationship of cobalt-based catalysts for the carbon monoxide hydrogenation is as old as the reaction itself. Here the authors show kinetic hysteresis for a potassium-promoted cobalt-manganese oxide catalyst to be driven by the Co-Co2C phase transition.
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Publishing Group
2019-09-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-019-11836-z |
| Summary: | The question for the structure-reactivity relationship of cobalt-based catalysts for the carbon monoxide hydrogenation is as old as the reaction itself. Here the authors show kinetic hysteresis for a potassium-promoted cobalt-manganese oxide catalyst to be driven by the Co-Co2C phase transition. |
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| ISSN: | 2041-1723 |