Di-μ-chlorido-bis{[4-amino-3,5-bis(2-pyridyl)-4H-1,2,4-triazole-κN1]chloridomercury(II)}

Di-μ-chlorido-bis{[4-amino-3,5-bis(2-pyridyl)-4H-1,2,4-triazole-κN1]chloridomercury(II)}

In the centrosymmetric binuclear title complex, [Hg2Cl4(C12H10N6)2], the HgII ion is five-coordinated by two N atoms and three chloride ions with a distorted square-pyramidal geometry. In the complex, there is an intramolecular N—H...N hydrogen bond. In the crystal, the binuclear units...

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Main Authors: Jian Guo, Min Tang, Jing Chen, Cheng-Peng Li
Format: Article
Language:English
Published: International Union of Crystallography 2011-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811029886
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spelling doaj-7be932c3d8cb4ff59ef58a1d249970e12020-11-25T01:35:45ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-09-01679m1180m118010.1107/S1600536811029886Di-μ-chlorido-bis{[4-amino-3,5-bis(2-pyridyl)-4H-1,2,4-triazole-κN1]chloridomercury(II)}Jian GuoMin TangJing ChenCheng-Peng LiIn the centrosymmetric binuclear title complex, [Hg2Cl4(C12H10N6)2], the HgII ion is five-coordinated by two N atoms and three chloride ions with a distorted square-pyramidal geometry. In the complex, there is an intramolecular N—H...N hydrogen bond. In the crystal, the binuclear units are connected by intermolecular N—H...Cl hydrogen bonds, as well as π–π stacking interactions [centroid–centroid distances = 3.526 (2) and 3.696 (2) Å], forming a two-dimensional layered structure parallel to (010).http://scripts.iucr.org/cgi-bin/paper?S1600536811029886
collection DOAJ
language English
format Article
sources DOAJ
author Jian Guo
Min Tang
Jing Chen
Cheng-Peng Li
spellingShingle Jian Guo
Min Tang
Jing Chen
Cheng-Peng Li
Di-μ-chlorido-bis{[4-amino-3,5-bis(2-pyridyl)-4H-1,2,4-triazole-κN1]chloridomercury(II)}
Acta Crystallographica Section E
author_facet Jian Guo
Min Tang
Jing Chen
Cheng-Peng Li
author_sort Jian Guo
title Di-μ-chlorido-bis{[4-amino-3,5-bis(2-pyridyl)-4H-1,2,4-triazole-κN1]chloridomercury(II)}
title_short Di-μ-chlorido-bis{[4-amino-3,5-bis(2-pyridyl)-4H-1,2,4-triazole-κN1]chloridomercury(II)}
title_full Di-μ-chlorido-bis{[4-amino-3,5-bis(2-pyridyl)-4H-1,2,4-triazole-κN1]chloridomercury(II)}
title_fullStr Di-μ-chlorido-bis{[4-amino-3,5-bis(2-pyridyl)-4H-1,2,4-triazole-κN1]chloridomercury(II)}
title_full_unstemmed Di-μ-chlorido-bis{[4-amino-3,5-bis(2-pyridyl)-4H-1,2,4-triazole-κN1]chloridomercury(II)}
title_sort di-μ-chlorido-bis{[4-amino-3,5-bis(2-pyridyl)-4h-1,2,4-triazole-κn1]chloridomercury(ii)}
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-09-01
description In the centrosymmetric binuclear title complex, [Hg2Cl4(C12H10N6)2], the HgII ion is five-coordinated by two N atoms and three chloride ions with a distorted square-pyramidal geometry. In the complex, there is an intramolecular N—H...N hydrogen bond. In the crystal, the binuclear units are connected by intermolecular N—H...Cl hydrogen bonds, as well as π–π stacking interactions [centroid–centroid distances = 3.526 (2) and 3.696 (2) Å], forming a two-dimensional layered structure parallel to (010).
url http://scripts.iucr.org/cgi-bin/paper?S1600536811029886
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AT jingchen diamp956chloridobis4amino35bis2pyridyl4h124triazoleamp954n1chloridomercuryii
AT chengpengli diamp956chloridobis4amino35bis2pyridyl4h124triazoleamp954n1chloridomercuryii
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