A novel lithium copper iron phosphate with idealized formula Li5Cu22+Fe3+(PO4)4: crystal structure and distribution of defects
Gray–green single crystals were obtained under high-pressure, high-temperature hydrothermal conditions. A refinement of atom occupancies gave the composition Li3.68Cu2+Fe3+(Cu0.55Li0.45)2Fe2+0.15(PO4)4. The structure is built from triplets of edge-sharing (Cu,Li)O5–FeO6&a...
Main Authors: | , , , |
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Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2011-05-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811011755 |