2-[(1H-Benzimidazol-2-yl)iminomethyl]-4,6-dibromophenol ethanol hemisolvate

2-[(1H-Benzimidazol-2-yl)iminomethyl]-4,6-dibromophenol ethanol hemisolvate

The title compound, C14H9Br2N3O·0.5C2H5OH, crystallizes with two 2-[(1H-benzimidazol-2-yl)iminomethyl]-4,6-dibromophenol molecules and one ethanol solvent molecule in the asymmetric unit. The benzene and benzimidazole rings subtend dihedral angles of 4.5 (3) and 5.2 (2)&...

Full description

Bibliographic Details
Main Authors: Shuai Yuan, Zheng Liu, Jie Liu
Format: Article
Language:English
Published: International Union of Crystallography 2013-03-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536813002031
id doaj-7b553cbcd04c4eadbd7f877ca5e19901
record_format Article
spelling doaj-7b553cbcd04c4eadbd7f877ca5e199012020-11-24T22:09:35ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-03-01693o362o36210.1107/S16005368130020312-[(1H-Benzimidazol-2-yl)iminomethyl]-4,6-dibromophenol ethanol hemisolvateShuai YuanZheng LiuJie LiuThe title compound, C14H9Br2N3O·0.5C2H5OH, crystallizes with two 2-[(1H-benzimidazol-2-yl)iminomethyl]-4,6-dibromophenol molecules and one ethanol solvent molecule in the asymmetric unit. The benzene and benzimidazole rings subtend dihedral angles of 4.5 (3) and 5.2 (2)° in the two molecules. In the crystal, one molecule presents π–π stacking with the equivalent molecule related by inversion, at a distance of 3.30 Å (separation between molecular mean planes). A three-dimensional network is formed through N—H...N, N—H...O and O—H...N hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536813002031
collection DOAJ
language English
format Article
sources DOAJ
author Shuai Yuan
Zheng Liu
Jie Liu
spellingShingle Shuai Yuan
Zheng Liu
Jie Liu
2-[(1H-Benzimidazol-2-yl)iminomethyl]-4,6-dibromophenol ethanol hemisolvate
Acta Crystallographica Section E
author_facet Shuai Yuan
Zheng Liu
Jie Liu
author_sort Shuai Yuan
title 2-[(1H-Benzimidazol-2-yl)iminomethyl]-4,6-dibromophenol ethanol hemisolvate
title_short 2-[(1H-Benzimidazol-2-yl)iminomethyl]-4,6-dibromophenol ethanol hemisolvate
title_full 2-[(1H-Benzimidazol-2-yl)iminomethyl]-4,6-dibromophenol ethanol hemisolvate
title_fullStr 2-[(1H-Benzimidazol-2-yl)iminomethyl]-4,6-dibromophenol ethanol hemisolvate
title_full_unstemmed 2-[(1H-Benzimidazol-2-yl)iminomethyl]-4,6-dibromophenol ethanol hemisolvate
title_sort 2-[(1h-benzimidazol-2-yl)iminomethyl]-4,6-dibromophenol ethanol hemisolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2013-03-01
description The title compound, C14H9Br2N3O·0.5C2H5OH, crystallizes with two 2-[(1H-benzimidazol-2-yl)iminomethyl]-4,6-dibromophenol molecules and one ethanol solvent molecule in the asymmetric unit. The benzene and benzimidazole rings subtend dihedral angles of 4.5 (3) and 5.2 (2)° in the two molecules. In the crystal, one molecule presents π–π stacking with the equivalent molecule related by inversion, at a distance of 3.30 Å (separation between molecular mean planes). A three-dimensional network is formed through N—H...N, N—H...O and O—H...N hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S1600536813002031
work_keys_str_mv AT shuaiyuan 21hbenzimidazol2yliminomethyl46dibromophenolethanolhemisolvate
AT zhengliu 21hbenzimidazol2yliminomethyl46dibromophenolethanolhemisolvate
AT jieliu 21hbenzimidazol2yliminomethyl46dibromophenolethanolhemisolvate
_version_ 1725811113510043648

Similar Items