Tricaesium dimolybdate(VI) bromide

Tricaesium dimolybdate(VI) bromide

The title compound, Cs3(Mo2O7)Br, was synthesized by the reaction of CsNO3, MoO3 and 1-ethyl-3-methylimidazolium bromide. Its crystal structure is isotypic with K3(Mo2O7)Br and contains (MoO4)2− tetrahedra which share an O atom to produce a [Mo2O7]2− dimolybdate(VI) anion...

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Main Authors: Anna S. Pakhomova, Sergey V. Krivovichev
Format: Article
Language:English
Published: International Union of Crystallography 2009-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809046297
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spelling doaj-7b5061c956054b398db0d1654fd31d482020-11-25T00:14:19ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-12-016512i87i8710.1107/S1600536809046297Tricaesium dimolybdate(VI) bromideAnna S. PakhomovaSergey V. KrivovichevThe title compound, Cs3(Mo2O7)Br, was synthesized by the reaction of CsNO3, MoO3 and 1-ethyl-3-methylimidazolium bromide. Its crystal structure is isotypic with K3(Mo2O7)Br and contains (MoO4)2− tetrahedra which share an O atom to produce a [Mo2O7]2− dimolybdate(VI) anion with a linear bridging angle and overline{6}m2 symmetry. The anions are linked by Cs atoms (site symmetry overline{6}m2), forming sheets parallel to (001). Br atoms (site symmetry overline{6}m2) are also part of this layer. Another type of Cs atom (3m site symmetry) is located in the interlayer space and connects the layers via Cs—O and Cs—Br interactions into a three-dimensional array. http://scripts.iucr.org/cgi-bin/paper?S1600536809046297
collection DOAJ
language English
format Article
sources DOAJ
author Anna S. Pakhomova
Sergey V. Krivovichev
spellingShingle Anna S. Pakhomova
Sergey V. Krivovichev
Tricaesium dimolybdate(VI) bromide
Acta Crystallographica Section E
author_facet Anna S. Pakhomova
Sergey V. Krivovichev
author_sort Anna S. Pakhomova
title Tricaesium dimolybdate(VI) bromide
title_short Tricaesium dimolybdate(VI) bromide
title_full Tricaesium dimolybdate(VI) bromide
title_fullStr Tricaesium dimolybdate(VI) bromide
title_full_unstemmed Tricaesium dimolybdate(VI) bromide
title_sort tricaesium dimolybdate(vi) bromide
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-12-01
description The title compound, Cs3(Mo2O7)Br, was synthesized by the reaction of CsNO3, MoO3 and 1-ethyl-3-methylimidazolium bromide. Its crystal structure is isotypic with K3(Mo2O7)Br and contains (MoO4)2− tetrahedra which share an O atom to produce a [Mo2O7]2− dimolybdate(VI) anion with a linear bridging angle and overline{6}m2 symmetry. The anions are linked by Cs atoms (site symmetry overline{6}m2), forming sheets parallel to (001). Br atoms (site symmetry overline{6}m2) are also part of this layer. Another type of Cs atom (3m site symmetry) is located in the interlayer space and connects the layers via Cs—O and Cs—Br interactions into a three-dimensional array.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809046297
work_keys_str_mv AT annaspakhomova tricaesiumdimolybdatevibromide
AT sergeyvkrivovichev tricaesiumdimolybdatevibromide
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