Tricaesium dimolybdate(VI) bromide
The title compound, Cs3(Mo2O7)Br, was synthesized by the reaction of CsNO3, MoO3 and 1-ethyl-3-methylimidazolium bromide. Its crystal structure is isotypic with K3(Mo2O7)Br and contains (MoO4)2− tetrahedra which share an O atom to produce a [Mo2O7]2− dimolybdate(VI) anion...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-12-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809046297 |
| Summary: | The title compound, Cs3(Mo2O7)Br, was synthesized by the reaction of CsNO3, MoO3 and 1-ethyl-3-methylimidazolium bromide. Its crystal structure is isotypic with K3(Mo2O7)Br and contains (MoO4)2− tetrahedra which share an O atom to produce a [Mo2O7]2− dimolybdate(VI) anion with a linear bridging angle and overline{6}m2 symmetry. The anions are linked by Cs atoms (site symmetry overline{6}m2), forming sheets parallel to (001). Br atoms (site symmetry overline{6}m2) are also part of this layer. Another type of Cs atom (3m site symmetry) is located in the interlayer space and connects the layers via Cs—O and Cs—Br interactions into a three-dimensional array. |
|---|---|
| ISSN: | 1600-5368 |