Bis[2-(4-aminophenyl)-4,5-dihydro-1H-imidazol-3-ium] dichloride monohydrate

Bis[2-(4-aminophenyl)-4,5-dihydro-1H-imidazol-3-ium] dichloride monohydrate

The asymmetric unit of the title compound, 2C9H12N3+·2Cl−·H2O, comprises two molecules, two chloride anions and one molecule of crystal water. In the imidazolinium ring, the protonation contributes to delocalization of the positive charge over the two C&am...

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Main Authors: Krešimir Molčanov, Ivana Stolić, Biserka Kojić-Prodić, Miroslav Bajić
Format: Article
Language:English
Published: International Union of Crystallography 2011-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811050070
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spelling doaj-7b1f3176bce045d3b32588cd0966004c2020-11-25T00:55:54ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-12-016712o3450o345110.1107/S1600536811050070Bis[2-(4-aminophenyl)-4,5-dihydro-1H-imidazol-3-ium] dichloride monohydrateKrešimir MolčanovIvana StolićBiserka Kojić-ProdićMiroslav BajićThe asymmetric unit of the title compound, 2C9H12N3+·2Cl−·H2O, comprises two molecules, two chloride anions and one molecule of crystal water. In the imidazolinium ring, the protonation contributes to delocalization of the positive charge over the two C—N bonds. Both chloride anions are acceptors of four hydrogen bonds in a flattened tetrahedron environment. The donors are NH2 groups, the NH groups of the imidazolinium rings and the water molecule. These hydrogen bonds and N—H...O(H2O) hydrogen bonds form a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536811050070
collection DOAJ
language English
format Article
sources DOAJ
author Krešimir Molčanov
Ivana Stolić
Biserka Kojić-Prodić
Miroslav Bajić
spellingShingle Krešimir Molčanov
Ivana Stolić
Biserka Kojić-Prodić
Miroslav Bajić
Bis[2-(4-aminophenyl)-4,5-dihydro-1H-imidazol-3-ium] dichloride monohydrate
Acta Crystallographica Section E
author_facet Krešimir Molčanov
Ivana Stolić
Biserka Kojić-Prodić
Miroslav Bajić
author_sort Krešimir Molčanov
title Bis[2-(4-aminophenyl)-4,5-dihydro-1H-imidazol-3-ium] dichloride monohydrate
title_short Bis[2-(4-aminophenyl)-4,5-dihydro-1H-imidazol-3-ium] dichloride monohydrate
title_full Bis[2-(4-aminophenyl)-4,5-dihydro-1H-imidazol-3-ium] dichloride monohydrate
title_fullStr Bis[2-(4-aminophenyl)-4,5-dihydro-1H-imidazol-3-ium] dichloride monohydrate
title_full_unstemmed Bis[2-(4-aminophenyl)-4,5-dihydro-1H-imidazol-3-ium] dichloride monohydrate
title_sort bis[2-(4-aminophenyl)-4,5-dihydro-1h-imidazol-3-ium] dichloride monohydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-12-01
description The asymmetric unit of the title compound, 2C9H12N3+·2Cl−·H2O, comprises two molecules, two chloride anions and one molecule of crystal water. In the imidazolinium ring, the protonation contributes to delocalization of the positive charge over the two C—N bonds. Both chloride anions are acceptors of four hydrogen bonds in a flattened tetrahedron environment. The donors are NH2 groups, the NH groups of the imidazolinium rings and the water molecule. These hydrogen bonds and N—H...O(H2O) hydrogen bonds form a three-dimensional network.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811050070
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AT ivanastoliamp263 bis24aminophenyl45dihydro1himidazol3iumdichloridemonohydrate
AT biserkakojiamp263prodiamp263 bis24aminophenyl45dihydro1himidazol3iumdichloridemonohydrate
AT miroslavbajiamp263 bis24aminophenyl45dihydro1himidazol3iumdichloridemonohydrate
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