Effect of the Fluorination of Graphene Nanoflake on the Dispersion and Mechanical Properties of Polypropylene Nanocomposites

In order to investigate the effect of fluorination of graphene nanoflake on the dispersibility in polypropylene (PP) composites, fluorinated graphene oxide (FGO) was prepared by solvo-thermal reaction and applied as a filler of the PP nanocomposite. Due to the weakened inter-particle attraction amon...

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Main Authors: Min Gyu Lee, Sangwoon Lee, Jaehyun Cho, Seokyoung Bae, Jae Young Jho
Format: Article
Language:English
Published: MDPI AG 2020-06-01
Series:Nanomaterials
Subjects:
Online Access:https://www.mdpi.com/2079-4991/10/6/1171
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spelling doaj-7aeeead131ce4f1db947419f82438cfb2020-11-25T03:13:14ZengMDPI AGNanomaterials2079-49912020-06-01101171117110.3390/nano10061171Effect of the Fluorination of Graphene Nanoflake on the Dispersion and Mechanical Properties of Polypropylene NanocompositesMin Gyu Lee0Sangwoon Lee1Jaehyun Cho2Seokyoung Bae3Jae Young Jho4School of Chemical and Biological Engineering, Seoul National University, Seoul 08826, KoreaSchool of Chemical and Biological Engineering, Seoul National University, Seoul 08826, KoreaInstitute of Advanced Composite Materials, Korea Institute of Science and Technology, Jeonbuk 54896, KoreaSchool of Chemical and Biological Engineering, Seoul National University, Seoul 08826, KoreaSchool of Chemical and Biological Engineering, Seoul National University, Seoul 08826, KoreaIn order to investigate the effect of fluorination of graphene nanoflake on the dispersibility in polypropylene (PP) composites, fluorinated graphene oxide (FGO) was prepared by solvo-thermal reaction and applied as a filler of the PP nanocomposite. Due to the weakened inter-particle attraction among the graphene nanoflake and reduced surface energy difference between PP and the filler, PP/FGO composites showed better exfoliation and dispersion state of the filler compared with that of PP/graphene oxide (GO) or PP/reduced graphene oxide (RGO) composites. The improved exfoliation and dispersion of graphene nanoflake resulted in a significant reinforcement on the composites. The Young’s modulus and tensile strength of PP composites filled with 2 wt% of FGO increased by 31% and 15%, respectively, compared with those of PP.https://www.mdpi.com/2079-4991/10/6/1171polypropylenefluorinated graphene oxidesurface energydispersionmechanical property
collection DOAJ
language English
format Article
sources DOAJ
author Min Gyu Lee
Sangwoon Lee
Jaehyun Cho
Seokyoung Bae
Jae Young Jho
spellingShingle Min Gyu Lee
Sangwoon Lee
Jaehyun Cho
Seokyoung Bae
Jae Young Jho
Effect of the Fluorination of Graphene Nanoflake on the Dispersion and Mechanical Properties of Polypropylene Nanocomposites
Nanomaterials
polypropylene
fluorinated graphene oxide
surface energy
dispersion
mechanical property
author_facet Min Gyu Lee
Sangwoon Lee
Jaehyun Cho
Seokyoung Bae
Jae Young Jho
author_sort Min Gyu Lee
title Effect of the Fluorination of Graphene Nanoflake on the Dispersion and Mechanical Properties of Polypropylene Nanocomposites
title_short Effect of the Fluorination of Graphene Nanoflake on the Dispersion and Mechanical Properties of Polypropylene Nanocomposites
title_full Effect of the Fluorination of Graphene Nanoflake on the Dispersion and Mechanical Properties of Polypropylene Nanocomposites
title_fullStr Effect of the Fluorination of Graphene Nanoflake on the Dispersion and Mechanical Properties of Polypropylene Nanocomposites
title_full_unstemmed Effect of the Fluorination of Graphene Nanoflake on the Dispersion and Mechanical Properties of Polypropylene Nanocomposites
title_sort effect of the fluorination of graphene nanoflake on the dispersion and mechanical properties of polypropylene nanocomposites
publisher MDPI AG
series Nanomaterials
issn 2079-4991
publishDate 2020-06-01
description In order to investigate the effect of fluorination of graphene nanoflake on the dispersibility in polypropylene (PP) composites, fluorinated graphene oxide (FGO) was prepared by solvo-thermal reaction and applied as a filler of the PP nanocomposite. Due to the weakened inter-particle attraction among the graphene nanoflake and reduced surface energy difference between PP and the filler, PP/FGO composites showed better exfoliation and dispersion state of the filler compared with that of PP/graphene oxide (GO) or PP/reduced graphene oxide (RGO) composites. The improved exfoliation and dispersion of graphene nanoflake resulted in a significant reinforcement on the composites. The Young’s modulus and tensile strength of PP composites filled with 2 wt% of FGO increased by 31% and 15%, respectively, compared with those of PP.
topic polypropylene
fluorinated graphene oxide
surface energy
dispersion
mechanical property
url https://www.mdpi.com/2079-4991/10/6/1171
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