Dechlorination of p-Chlorophenol by Fe-Pd Nanoparticles Promoted by Poly (γ-glutamic acid)–Dopamine Composite
Palladium-doped nanoscale zerovalent iron nanoparticles (Fe-Pd NPs) was fabricated and stabilized by poly (γ-glutamic acid)–Dopamine composite (PGA-DA). The fabricated nanoparticles had high dechlorination activity towards p-Chlorophenol (p-CP). PGA-DA modified Fe-Pd NPs significantly outperformed P...
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
AIDIC Servizi S.r.l.
2018-08-01
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| Series: | Chemical Engineering Transactions |
| Online Access: | https://www.cetjournal.it/index.php/cet/article/view/780 |
| Summary: | Palladium-doped nanoscale zerovalent iron nanoparticles (Fe-Pd NPs) was fabricated and stabilized by poly (γ-glutamic acid)–Dopamine composite (PGA-DA). The fabricated nanoparticles had high dechlorination activity towards p-Chlorophenol (p-CP). PGA-DA modified Fe-Pd NPs significantly outperformed PGA modified ones in catalytic activities even in weak alkaline condition. Fe-Pd NPs@PGA-DA (10 mg PGA-DA and 0.4 wt% Pd loading) could achieve 100 % p-CP removal within 60 min. It is worth mentioning that the presence of DA alone could overwhelm dechlorination capacity of Fe-Pd NPs toward p-CP. The coordination bonding between catechol and Fe ions was also investigated in detail. This study demonstrated that PGA-DA is a promising modifier and stabilizer for Fe-Pd NPs, which was expected to be applied in real environmental remediation technology.
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| ISSN: | 2283-9216 |