Poly[bis(μ2-3-carboxybenzoato)bis(dipyrido[3,2-a;2′,3′-c]phenazine)bis(μ3-isophthalato)tricopper(II)]

Poly[bis(μ2-3-carboxybenzoato)bis(dipyrido[3,2-a;2′,3′-c]phenazine)bis(μ3-isophthalato)tricopper(II)]

In the title compound, [Cu3(C8H4O4)2(C8H5O4)2(C18H10N4)2]n, one CuII atom, located on an inversion center, is hexacoordinated and shows a distorted octahedral coordination geometry, while the other CuII atom is pentacoordinated and exhibits a distorted square-pyramidal geometry. The CuII atoms are b...

Full description

Bibliographic Details
Main Author: Xiao-Fang Wang
Format: Article
Language:English
Published: International Union of Crystallography 2011-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811008993
Description
Summary:In the title compound, [Cu3(C8H4O4)2(C8H5O4)2(C18H10N4)2]n, one CuII atom, located on an inversion center, is hexacoordinated and shows a distorted octahedral coordination geometry, while the other CuII atom is pentacoordinated and exhibits a distorted square-pyramidal geometry. The CuII atoms are bridged by isophthalate and 3-carboxybenzoate ligands, forming a chain structure along the b axis. Furthermore, the chains are linked by O—H...O hydrogen bonds, forming a layer parallel to the ab plane.
ISSN:1600-5368

Similar Items