Redox initiation in semicontinuous polymerization to search for specific mechanical properties of copolymers

Redox initiation in semicontinuous polymerization to search for specific mechanical properties of copolymers

In this work, for a semicontinuous emulsion polymerization reaction, it is shown that using a redox initiation system at 40°C, substantial modifications in copolymer chain composition with conversion can be easily obtained. To test controllable trajectories for comonomer feeding, linear and paraboli...

Full description

Bibliographic Details
Main Authors:	Sandoval-Díaz José Manuel, Rivera-Gálvez Francisco Javier, Fernández-García Marta, Jasso-Gastinel Carlos Federico
Format:	Article
Language:	English
Published:	De Gruyter 2020-11-01
Series:	e-Polymers
Subjects:	redox initiation semicontinuous emulsion polymerization comonomer feed profiles gradient composition mechanical properties
Online Access:	http://www.degruyter.com/view/j/epoly.2020.20.issue-1/epoly-2020-0065/epoly-2020-0065.xml?format=INT

Similar Items

Tailoring Copolymer Properties by Gradual Changes in the Distribution of the Chains Composition Using Semicontinuous Emulsion Polymerization
by: Carlos Federico Jasso-Gastinel, et al.
Published: (2017-02-01)

Effect of Monomer Dosing Rate in the Preparation of Mesoporous Polystyrene Nanoparticles by Semicontinuous Heterophase Polymerization
by: Dalia Y. Sosa, et al.
Published: (2014-12-01)

Consistently Semicontinuous Dcpo
by: Wang Di, et al.
Published: (2016-01-01)

A note on almost δ-semicontinuous functions
by: Takashi Noiri, et al.
Published: (2008-11-01)

Semicontinuity and closedness of parametric generalized lexicographic quasiequilibrium problems
by: Rabian Wangkeeree, et al.
Published: (2016-02-01)

Effect of Hydrogen and Comonomer on the Kinetics of Slurry Polymerization of Ethylene and Properties of Produced Polyethylene over TiCl4/MgCl2/AlEt3 Catalyst
by: mahshid Mashhadi-Hasan-Shirazi, et al.
Published: (2013-01-01)

Improvement in Wood Bonding Strength of Poly (Vinyl Acetate-Butyl Acrylate) Emulsion by Controlling the Amount of Redox Initiator
by: Yun Zhang, et al.
Published: (2018-01-01)

Kinetics of Waterborne Alkyd/Acrylic Hybrid Resin Free Radical Polymerization by Two Systems of Redox and Thermal Initiators
by: shirin Madadi, et al.
Published: (2012-12-01)

New Pure Organic and Peroxide-Free Redox Initiating Systems for Polymerization in Mild Conditions
by: Ahmad Arar, et al.
Published: (2021-01-01)

Tailored Chain Sequences of Brominated Syndiotactic Polystyrene Copolymers via Post-Polymerization Functionalization in the Heterogeneous Gel State
by: Noble, Kristen Felice
Published: (2019)

Influence Of Initiator Types And Emulsion Polymerization Techniques To Particle Size Of Copolymerization Styrene-Butyl Acrylate-Methyl Methacrylate
by: Ariyanti Sarwono, et al.
Published: (2008-11-01)

Weak lower semicontinuity of variational functionals with variable growth
by: Yongqiang Fu
Published: (2011-01-01)

Synthesis and Optoelectronic Properties of Block and Random Copolymers Containing Pendant Carbazole and (Di)phenylanthracene
by: Chen-Tsyr Lo, et al.
Published: (2018-07-01)

Maximal Classes For Lower And Upper Semicontinuous Strong Świątkowski Functions
by: Szczuka Paulina
Published: (2014-03-01)

Upper semicontinuity of pullback attractors for a nonautonomous damped wave equation
by: Yonghai Wang, et al.
Published: (2021-06-01)

Semicontinuous cultivation of the cyanobacterium Spirulina platensis in a closed photobioreactor
by: C. C. Reichert, et al.
Published: (2006-03-01)

On the upper semicontinuity of global attractors for damped wave equations
by: Joseph L. Shomberg
Published: (2017-09-01)

Upper semicontinuity of uniform attractors for nonclassical diffusion equations
by: Yonghai Wang, et al.
Published: (2017-06-01)

Existence and upper semicontinuity of global attractors for neural fields in an unbounded domain
by: Severino Horacio Da Silva
Published: (2010-09-01)

CONTINUOUS AND SEMICONTINUOUS REACTION SYSTEMS FOR HIGH-SOLIDS ENZYMATIC HYDROLYSIS OF LIGNOCELLULOSICS
by: A. González Quiroga, et al.
Published: (2015-12-01)

Iterative roots of upper semicontinuous multifunctions
by: Pingping Zhang, et al.
Published: (2017-11-01)

Initiator Systems Effect on Particle Coagulation and Particle Size Distribution in One-Step Emulsion Polymerization of Styrene
by: Baijun Liu, et al.
Published: (2016-02-01)

Precipitated Calcium Carbonate Prepared by Batch and Semicontinuous Processes
by: Brečević; Lj., et al.
Published: (2007-07-01)

SYNTHESIS AND CHARACTERIZATION OF GRAFT COPOLYMERS OF 2-HYDROXYETHYL METHACRYLATE AND SOME COMONOMERS ONTO EXTRACTED CELLULOSE FOR USE IN SEPARATION TECHNOLOGIES
by: Rajeev Kumar Sharma, et al.
Published: (2009-08-01)

Production of bio-inseticide Bacillus thuringiensis var. israelensis in semicontinuous processes combined with batch processes for sporulation
by: Millena da Silva, et al.
Published: (2011-02-01)

Lower semicontinuity of pullback attractors for a singularly nonautonomous plate equation
by: Ricardo Parreira da Silva
Published: (2012-10-01)

Existence and upper semicontinuity of global attractors for a $p$-Laplacian inclusion
by: Jacson Simsen, et al.
Published: (2015-05-01)

Synthesis of Poly(methyl methacrylate)-<i>b</i>-poly(<i>N</i>-isopropylacrylamide) Block Copolymer by Redox Polymerization and Atom Transfer Radical Polymerization
by: Melahat Göktaş, et al.
Published: (2018-08-01)

A Note on the Topological Transversality Theorem for Weakly Upper Semicontinuous, Weakly Compact Maps on Locally Convex Topological Vector Spaces
by: Donal O’Regan
Published: (2020-02-01)

Fructose-Based Acrylic Copolymers by Emulsion Polymerization
by: Jessica S. Desport, et al.
Published: (2018-05-01)

A molecular level investigation of hybrid miniemulsion polymerization
by: Tsavalas, John George
Published: (2006)

Particle nucleation and growth in a polymerically stabilized emulsion polymerization system
by: Gilmore, Cheryl Matthews
Published: (2006)

Upper semicontinuity of random attractors for non-compact random dynamical systems
by: Bixiang Wang
Published: (2009-10-01)

Continuous miniemulsion polymerization
by: Barnette, Darrell Thomas
Published: (2006)

Upper semicontinuity of attractors for nonclassical diffusion equations with arbitrary polynomial growth
by: Yongqin Xie, et al.
Published: (2021-01-01)

Multiscale semicontinuous thin film descriptors
by: Boldyš Jiří, et al.
Published: (2004-12-01)

A New Insight into the Comonomer Effect through NMR Analysis in Metallocene Catalysed Propene–<i>co</i>–1-Nonene Copolymers
by: Qiong Wu, et al.
Published: (2019-07-01)

Some characterizations of error bound for non-lower semicontinuous functions
by: Miantao Chao, et al.
Published: (2019-02-01)

Synthesis of Polypyrrole Induced by [Fe(CN)6]3− and Redox Cycling of [Fe(CN)6]4−/[Fe(CN)6]3−
by: Eivydas Andriukonis, et al.
Published: (2018-07-01)

Production of Poly-γ-Glutamate (PGA) Biopolymer by Batch and Semicontinuous Cultures of Immobilized Bacilluslicheniformis strain-R
by: Mahmoud M. Berekaa, et al.
Published: (2009-12-01)

Cannot write session to /tmp/vufind_sessions/sess_7c88ed9o3cec5aite4aln03l3e