Poly[[bis[μ2-8-ethyl-5-oxo-2-(piperazin-1-yl)-5,8-dihydropyrido[2,3-d]pyrimidine-6-carboxylato]manganese(II)] dihydrate]

Poly[[bis[μ2-8-ethyl-5-oxo-2-(piperazin-1-yl)-5,8-dihydropyrido[2,3-d]pyrimidine-6-carboxylato]manganese(II)] dihydrate]

In the title compound, {[Mn(C14H16N5O3)2]·2H2O}n, the MnII atom (site symmetry overline{1}) exhibits a distorted trans-MnN2O4 octahedral geometry defined by two monodentate N-bonded and two bidentate O,O′-bonded 8-ethyl-5-oxo-2-(piperazin-1-yl)-5,8-dihydropyrido[2,3-d]pyrimidine-6...

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Main Authors: Zhe An, Wei-Ping Hu, Jing Huang
Format: Article
Language:English
Published: International Union of Crystallography 2008-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808006533
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record_format Article
spelling doaj-7931edf9fba844c58a2313464c583d772020-11-25T02:46:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-04-01644m547m54710.1107/S1600536808006533Poly[[bis[μ2-8-ethyl-5-oxo-2-(piperazin-1-yl)-5,8-dihydropyrido[2,3-d]pyrimidine-6-carboxylato]manganese(II)] dihydrate]Zhe AnWei-Ping HuJing HuangIn the title compound, {[Mn(C14H16N5O3)2]·2H2O}n, the MnII atom (site symmetry overline{1}) exhibits a distorted trans-MnN2O4 octahedral geometry defined by two monodentate N-bonded and two bidentate O,O′-bonded 8-ethyl-5-oxo-2-(piperazin-1-yl)-5,8-dihydropyrido[2,3-d]pyrimidine-6-carboxylate anions. An N—H...O hydrogen bond is present in the crystal structure. The extended two-dimensional structure is a square grid and the disordered uncoordinated water molecules occupy cavities within the grid.http://scripts.iucr.org/cgi-bin/paper?S1600536808006533
collection DOAJ
language English
format Article
sources DOAJ
author Zhe An
Wei-Ping Hu
Jing Huang
spellingShingle Zhe An
Wei-Ping Hu
Jing Huang
Poly[[bis[μ2-8-ethyl-5-oxo-2-(piperazin-1-yl)-5,8-dihydropyrido[2,3-d]pyrimidine-6-carboxylato]manganese(II)] dihydrate]
Acta Crystallographica Section E
author_facet Zhe An
Wei-Ping Hu
Jing Huang
author_sort Zhe An
title Poly[[bis[μ2-8-ethyl-5-oxo-2-(piperazin-1-yl)-5,8-dihydropyrido[2,3-d]pyrimidine-6-carboxylato]manganese(II)] dihydrate]
title_short Poly[[bis[μ2-8-ethyl-5-oxo-2-(piperazin-1-yl)-5,8-dihydropyrido[2,3-d]pyrimidine-6-carboxylato]manganese(II)] dihydrate]
title_full Poly[[bis[μ2-8-ethyl-5-oxo-2-(piperazin-1-yl)-5,8-dihydropyrido[2,3-d]pyrimidine-6-carboxylato]manganese(II)] dihydrate]
title_fullStr Poly[[bis[μ2-8-ethyl-5-oxo-2-(piperazin-1-yl)-5,8-dihydropyrido[2,3-d]pyrimidine-6-carboxylato]manganese(II)] dihydrate]
title_full_unstemmed Poly[[bis[μ2-8-ethyl-5-oxo-2-(piperazin-1-yl)-5,8-dihydropyrido[2,3-d]pyrimidine-6-carboxylato]manganese(II)] dihydrate]
title_sort poly[[bis[μ2-8-ethyl-5-oxo-2-(piperazin-1-yl)-5,8-dihydropyrido[2,3-d]pyrimidine-6-carboxylato]manganese(ii)] dihydrate]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-04-01
description In the title compound, {[Mn(C14H16N5O3)2]·2H2O}n, the MnII atom (site symmetry overline{1}) exhibits a distorted trans-MnN2O4 octahedral geometry defined by two monodentate N-bonded and two bidentate O,O′-bonded 8-ethyl-5-oxo-2-(piperazin-1-yl)-5,8-dihydropyrido[2,3-d]pyrimidine-6-carboxylate anions. An N—H...O hydrogen bond is present in the crystal structure. The extended two-dimensional structure is a square grid and the disordered uncoordinated water molecules occupy cavities within the grid.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808006533
work_keys_str_mv AT zhean polybis95628ethyl5oxo2piperazin1yl58dihydropyrido23dpyrimidine6carboxylatomanganeseiidihydrate
AT weipinghu polybis95628ethyl5oxo2piperazin1yl58dihydropyrido23dpyrimidine6carboxylatomanganeseiidihydrate
AT jinghuang polybis95628ethyl5oxo2piperazin1yl58dihydropyrido23dpyrimidine6carboxylatomanganeseiidihydrate
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