Bis[tris(phenanthroline-κ2N,N′)cobalt(II)] undecatungsto(VI)vanado(V)phosphate dihydrate

Bis[tris(phenanthroline-κ2N,N′)cobalt(II)] undecatungsto(VI)vanado(V)phosphate dihydrate

In the title hydrated salt, [Co(C12H8N2)3]2[PVW11O40]·2H2O, the complete Kegggin ion is generated by crystallographic inversion symmetry, which imposes statistical disorder on the O atoms of its central PO4 group. The V atom is statistically disordered over all the metal sites of the anion. In the c...

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Main Authors: Assia Hajsalem, Sameh Aoun, Aurelien Planchat, Mohamed Rzaigui, Samah Akriche Toumi
Format: Article
Language:English
Published: International Union of Crystallography 2014-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681400484X
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spelling doaj-78a6c61e3bb247228eeb2c6b6bb9bbd52020-11-25T02:15:24ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-04-01704m125m12610.1107/S160053681400484Xhb7203Bis[tris(phenanthroline-κ2N,N′)cobalt(II)] undecatungsto(VI)vanado(V)phosphate dihydrateAssia Hajsalem0Sameh Aoun1Aurelien Planchat2Mohamed Rzaigui3Samah Akriche Toumi4Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte, TunisiaLaboratoire CEISAM, UMR CNRS 6230, UFR des Sciences et des Techniques, 2 rue de la Houssinière, BP 92208, 44322 Nantes Cedex 03, FranceLaboratoire CEISAM, UMR CNRS 6230, UFR des Sciences et des Techniques, 2 rue de la Houssinière, BP 92208, 44322 Nantes Cedex 03, FranceLaboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte, TunisiaLaboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte, TunisiaIn the title hydrated salt, [Co(C12H8N2)3]2[PVW11O40]·2H2O, the complete Kegggin ion is generated by crystallographic inversion symmetry, which imposes statistical disorder on the O atoms of its central PO4 group. The V atom is statistically disordered over all the metal sites of the anion. In the cation, the Co2+ ion is coordinated by three bidentate 1,10-phenanthroline (phen) ligands, generating a distorted CoN6 octahedron. Possible very weak intramolecular C—H...π interactions occur in the cation. In the crystal, the components are linked by O—H...O and C—H...O interactions, building a three-dimensional network featuring one-dimensional voids along the c-axis direction.http://scripts.iucr.org/cgi-bin/paper?S160053681400484X
collection DOAJ
language English
format Article
sources DOAJ
author Assia Hajsalem
Sameh Aoun
Aurelien Planchat
Mohamed Rzaigui
Samah Akriche Toumi
spellingShingle Assia Hajsalem
Sameh Aoun
Aurelien Planchat
Mohamed Rzaigui
Samah Akriche Toumi
Bis[tris(phenanthroline-κ2N,N′)cobalt(II)] undecatungsto(VI)vanado(V)phosphate dihydrate
Acta Crystallographica Section E
author_facet Assia Hajsalem
Sameh Aoun
Aurelien Planchat
Mohamed Rzaigui
Samah Akriche Toumi
author_sort Assia Hajsalem
title Bis[tris(phenanthroline-κ2N,N′)cobalt(II)] undecatungsto(VI)vanado(V)phosphate dihydrate
title_short Bis[tris(phenanthroline-κ2N,N′)cobalt(II)] undecatungsto(VI)vanado(V)phosphate dihydrate
title_full Bis[tris(phenanthroline-κ2N,N′)cobalt(II)] undecatungsto(VI)vanado(V)phosphate dihydrate
title_fullStr Bis[tris(phenanthroline-κ2N,N′)cobalt(II)] undecatungsto(VI)vanado(V)phosphate dihydrate
title_full_unstemmed Bis[tris(phenanthroline-κ2N,N′)cobalt(II)] undecatungsto(VI)vanado(V)phosphate dihydrate
title_sort bis[tris(phenanthroline-κ2n,n′)cobalt(ii)] undecatungsto(vi)vanado(v)phosphate dihydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2014-04-01
description In the title hydrated salt, [Co(C12H8N2)3]2[PVW11O40]·2H2O, the complete Kegggin ion is generated by crystallographic inversion symmetry, which imposes statistical disorder on the O atoms of its central PO4 group. The V atom is statistically disordered over all the metal sites of the anion. In the cation, the Co2+ ion is coordinated by three bidentate 1,10-phenanthroline (phen) ligands, generating a distorted CoN6 octahedron. Possible very weak intramolecular C—H...π interactions occur in the cation. In the crystal, the components are linked by O—H...O and C—H...O interactions, building a three-dimensional network featuring one-dimensional voids along the c-axis direction.
url http://scripts.iucr.org/cgi-bin/paper?S160053681400484X
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