Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate-κ2O,O′}tris(thiocyanato-κN)lanthanum(III)

Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate-κ2O,O′}tris(thiocyanato-κN)lanthanum(III)

In the title compound, [La(NCS)3(C15H15NO2)3], the metal centre is nine-coordinated by six O atoms from three zwitterionic Schiff base 2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate (L) ligands and three terminal N atoms of the thiocyanate ions in a monocapped square-antiprismatic environment....

Full description

Bibliographic Details
Main Authors: Guo-Liang Zhao, Jia-Lu Liu, Jin-Bei Shen, Jian-Feng Liu
Format: Article
Language:English
Published: International Union of Crystallography 2009-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809049113
id doaj-780691f5a3164e478a216602c8476602
record_format Article
spelling doaj-780691f5a3164e478a216602c84766022020-11-24T20:47:11ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-12-016512m1650m165010.1107/S1600536809049113Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate-κ2O,O′}tris(thiocyanato-κN)lanthanum(III)Guo-Liang ZhaoJia-Lu LiuJin-Bei ShenJian-Feng LiuIn the title compound, [La(NCS)3(C15H15NO2)3], the metal centre is nine-coordinated by six O atoms from three zwitterionic Schiff base 2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate (L) ligands and three terminal N atoms of the thiocyanate ions in a monocapped square-antiprismatic environment. The L ligands chelate the LaIII ion with strong La—O(deprotonated phenolic) bonds [2.435 (3)–2.464 (3) Å] and significantly longer La—O(methoxy) bonds [2.801 (3)–2.831 (3) Å]. The La—N bond lengths range from 2.541 (4) to 2.605 (4) Å. http://scripts.iucr.org/cgi-bin/paper?S1600536809049113
collection DOAJ
language English
format Article
sources DOAJ
author Guo-Liang Zhao
Jia-Lu Liu
Jin-Bei Shen
Jian-Feng Liu
spellingShingle Guo-Liang Zhao
Jia-Lu Liu
Jin-Bei Shen
Jian-Feng Liu
Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate-κ2O,O′}tris(thiocyanato-κN)lanthanum(III)
Acta Crystallographica Section E
author_facet Guo-Liang Zhao
Jia-Lu Liu
Jin-Bei Shen
Jian-Feng Liu
author_sort Guo-Liang Zhao
title Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate-κ2O,O′}tris(thiocyanato-κN)lanthanum(III)
title_short Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate-κ2O,O′}tris(thiocyanato-κN)lanthanum(III)
title_full Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate-κ2O,O′}tris(thiocyanato-κN)lanthanum(III)
title_fullStr Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate-κ2O,O′}tris(thiocyanato-κN)lanthanum(III)
title_full_unstemmed Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate-κ2O,O′}tris(thiocyanato-κN)lanthanum(III)
title_sort tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate-κ2o,o′}tris(thiocyanato-κn)lanthanum(iii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-12-01
description In the title compound, [La(NCS)3(C15H15NO2)3], the metal centre is nine-coordinated by six O atoms from three zwitterionic Schiff base 2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolate (L) ligands and three terminal N atoms of the thiocyanate ions in a monocapped square-antiprismatic environment. The L ligands chelate the LaIII ion with strong La—O(deprotonated phenolic) bonds [2.435 (3)–2.464 (3) Å] and significantly longer La—O(methoxy) bonds [2.801 (3)–2.831 (3) Å]. The La—N bond lengths range from 2.541 (4) to 2.605 (4) Å.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809049113
work_keys_str_mv AT guoliangzhao tris2methoxy64methylphenyliminiomethylphenolateamp9542ooamp8242tristhiocyanatoamp954nlanthanumiii
AT jialuliu tris2methoxy64methylphenyliminiomethylphenolateamp9542ooamp8242tristhiocyanatoamp954nlanthanumiii
AT jinbeishen tris2methoxy64methylphenyliminiomethylphenolateamp9542ooamp8242tristhiocyanatoamp954nlanthanumiii
AT jianfengliu tris2methoxy64methylphenyliminiomethylphenolateamp9542ooamp8242tristhiocyanatoamp954nlanthanumiii
_version_ 1716810876622733312

Similar Items