Coordinated “Naked” Pnicogenes and Catalysis
Diphosphorous (P<sub>2</sub>) side-on coordinated to a dicobalt (Co⁻Co) moiety was described 45 years ago. This discovery had several links to actual problems of homogeneous molecular catalysis. The new type of organometallic complexes induced several ingenious new ramification...
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doaj-77cf873d02694988bcef27faf6135e092020-11-24T22:57:26ZengMDPI AGCatalysts2073-43442018-11-0181258310.3390/catal8120583catal8120583Coordinated “Naked” Pnicogenes and CatalysisAnna Vízi-Orosz0Gergely Berzeviczy1Gyula Pályi2Research Group for Petrochemistry of the Hungarian Academy of Sciences, H-8200 Veszprém, Egyetem u. 10, HungaryDepartment of Organic Chemistry, University of Pannonia, H-8200 Veszprém, Egyetem u. 10, HungaryDepartment of Life Sciences, University of Modena and Reggio Emilia, I-4125 Modena, Via Campi, 103, ItalyDiphosphorous (P<sub>2</sub>) side-on coordinated to a dicobalt (Co⁻Co) moiety was described 45 years ago. This discovery had several links to actual problems of homogeneous molecular catalysis. The new type of organometallic complexes induced several ingenious new ramifications in main-group/transition metal cluster chemistry in the last decades. The present review traces the main lines of these research results and their contacts to actual problems of industrial catalysis.https://www.mdpi.com/2073-4344/8/12/583heteronuclear transition metal clustersphosphorous-cobalt clustersarsenic-cobalt clustersmain group element–transition metal clusterscatalysis by clustershomogeneous catalysis |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Anna Vízi-Orosz Gergely Berzeviczy Gyula Pályi |
spellingShingle |
Anna Vízi-Orosz Gergely Berzeviczy Gyula Pályi Coordinated “Naked” Pnicogenes and Catalysis Catalysts heteronuclear transition metal clusters phosphorous-cobalt clusters arsenic-cobalt clusters main group element–transition metal clusters catalysis by clusters homogeneous catalysis |
author_facet |
Anna Vízi-Orosz Gergely Berzeviczy Gyula Pályi |
author_sort |
Anna Vízi-Orosz |
title |
Coordinated “Naked” Pnicogenes and Catalysis |
title_short |
Coordinated “Naked” Pnicogenes and Catalysis |
title_full |
Coordinated “Naked” Pnicogenes and Catalysis |
title_fullStr |
Coordinated “Naked” Pnicogenes and Catalysis |
title_full_unstemmed |
Coordinated “Naked” Pnicogenes and Catalysis |
title_sort |
coordinated “naked” pnicogenes and catalysis |
publisher |
MDPI AG |
series |
Catalysts |
issn |
2073-4344 |
publishDate |
2018-11-01 |
description |
Diphosphorous (P<sub>2</sub>) side-on coordinated to a dicobalt (Co⁻Co) moiety was described 45 years ago. This discovery had several links to actual problems of homogeneous molecular catalysis. The new type of organometallic complexes induced several ingenious new ramifications in main-group/transition metal cluster chemistry in the last decades. The present review traces the main lines of these research results and their contacts to actual problems of industrial catalysis. |
topic |
heteronuclear transition metal clusters phosphorous-cobalt clusters arsenic-cobalt clusters main group element–transition metal clusters catalysis by clusters homogeneous catalysis |
url |
https://www.mdpi.com/2073-4344/8/12/583 |
work_keys_str_mv |
AT annaviziorosz coordinatednakedpnicogenesandcatalysis AT gergelyberzeviczy coordinatednakedpnicogenesandcatalysis AT gyulapalyi coordinatednakedpnicogenesandcatalysis |
_version_ |
1725650847759597568 |