Coordinated “Naked” Pnicogenes and Catalysis

Diphosphorous (P<sub>2</sub>) side-on coordinated to a dicobalt (Co&#8315;Co) moiety was described 45 years ago. This discovery had several links to actual problems of homogeneous molecular catalysis. The new type of organometallic complexes induced several ingenious new ramification...

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Main Authors: Anna Vízi-Orosz, Gergely Berzeviczy, Gyula Pályi
Format: Article
Language:English
Published: MDPI AG 2018-11-01
Series:Catalysts
Subjects:
Online Access:https://www.mdpi.com/2073-4344/8/12/583
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spelling doaj-77cf873d02694988bcef27faf6135e092020-11-24T22:57:26ZengMDPI AGCatalysts2073-43442018-11-0181258310.3390/catal8120583catal8120583Coordinated “Naked” Pnicogenes and CatalysisAnna Vízi-Orosz0Gergely Berzeviczy1Gyula Pályi2Research Group for Petrochemistry of the Hungarian Academy of Sciences, H-8200 Veszprém, Egyetem u. 10, HungaryDepartment of Organic Chemistry, University of Pannonia, H-8200 Veszprém, Egyetem u. 10, HungaryDepartment of Life Sciences, University of Modena and Reggio Emilia, I-4125 Modena, Via Campi, 103, ItalyDiphosphorous (P<sub>2</sub>) side-on coordinated to a dicobalt (Co&#8315;Co) moiety was described 45 years ago. This discovery had several links to actual problems of homogeneous molecular catalysis. The new type of organometallic complexes induced several ingenious new ramifications in main-group/transition metal cluster chemistry in the last decades. The present review traces the main lines of these research results and their contacts to actual problems of industrial catalysis.https://www.mdpi.com/2073-4344/8/12/583heteronuclear transition metal clustersphosphorous-cobalt clustersarsenic-cobalt clustersmain group element–transition metal clusterscatalysis by clustershomogeneous catalysis
collection DOAJ
language English
format Article
sources DOAJ
author Anna Vízi-Orosz
Gergely Berzeviczy
Gyula Pályi
spellingShingle Anna Vízi-Orosz
Gergely Berzeviczy
Gyula Pályi
Coordinated “Naked” Pnicogenes and Catalysis
Catalysts
heteronuclear transition metal clusters
phosphorous-cobalt clusters
arsenic-cobalt clusters
main group element–transition metal clusters
catalysis by clusters
homogeneous catalysis
author_facet Anna Vízi-Orosz
Gergely Berzeviczy
Gyula Pályi
author_sort Anna Vízi-Orosz
title Coordinated “Naked” Pnicogenes and Catalysis
title_short Coordinated “Naked” Pnicogenes and Catalysis
title_full Coordinated “Naked” Pnicogenes and Catalysis
title_fullStr Coordinated “Naked” Pnicogenes and Catalysis
title_full_unstemmed Coordinated “Naked” Pnicogenes and Catalysis
title_sort coordinated “naked” pnicogenes and catalysis
publisher MDPI AG
series Catalysts
issn 2073-4344
publishDate 2018-11-01
description Diphosphorous (P<sub>2</sub>) side-on coordinated to a dicobalt (Co&#8315;Co) moiety was described 45 years ago. This discovery had several links to actual problems of homogeneous molecular catalysis. The new type of organometallic complexes induced several ingenious new ramifications in main-group/transition metal cluster chemistry in the last decades. The present review traces the main lines of these research results and their contacts to actual problems of industrial catalysis.
topic heteronuclear transition metal clusters
phosphorous-cobalt clusters
arsenic-cobalt clusters
main group element–transition metal clusters
catalysis by clusters
homogeneous catalysis
url https://www.mdpi.com/2073-4344/8/12/583
work_keys_str_mv AT annaviziorosz coordinatednakedpnicogenesandcatalysis
AT gergelyberzeviczy coordinatednakedpnicogenesandcatalysis
AT gyulapalyi coordinatednakedpnicogenesandcatalysis
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