1-[2,4,6-Trimethyl-3,5-bis(4-oxopiperidin-1-ylmethyl)benzyl]piperidin-4-one

1-[2,4,6-Trimethyl-3,5-bis(4-oxopiperidin-1-ylmethyl)benzyl]piperidin-4-one

In the structure of the title compound, C27H39N3O3, each of the (4-oxopiperidin-1-yl)methyl residues adopts a flattened chair conformation (with the N and carbonyl groups being oriented to either side of the central C4 plane) and they occupy positions approximately orthogonal to the central benzene...

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Main Authors: K. Rajesh, V. Vijayakumar, S. Sarveswari, T. Narasimhamurthy, Edward R. T. Tiekink
Format: Article
Language:English
Published: International Union of Crystallography 2010-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810016570
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spelling doaj-771f4e2ae06849bba8294952388ebfef2020-11-25T02:22:57ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-06-01666o1306o130710.1107/S16005368100165701-[2,4,6-Trimethyl-3,5-bis(4-oxopiperidin-1-ylmethyl)benzyl]piperidin-4-oneK. RajeshV. VijayakumarS. SarveswariT. NarasimhamurthyEdward R. T. TiekinkIn the structure of the title compound, C27H39N3O3, each of the (4-oxopiperidin-1-yl)methyl residues adopts a flattened chair conformation (with the N and carbonyl groups being oriented to either side of the central C4 plane) and they occupy positions approximately orthogonal to the central benzene ring [Cbenzene—C—Cmethylene—N torsion angles 103.4 (2), −104.4 (3) and 71.9 (3)°]; further, two of these residues are oriented to one side of the central benzene ring with the third to the other side. In the crystal packing, supramolecular layers in the ab plane are sustained by C—H...O interactions. http://scripts.iucr.org/cgi-bin/paper?S1600536810016570
collection DOAJ
language English
format Article
sources DOAJ
author K. Rajesh
V. Vijayakumar
S. Sarveswari
T. Narasimhamurthy
Edward R. T. Tiekink
spellingShingle K. Rajesh
V. Vijayakumar
S. Sarveswari
T. Narasimhamurthy
Edward R. T. Tiekink
1-[2,4,6-Trimethyl-3,5-bis(4-oxopiperidin-1-ylmethyl)benzyl]piperidin-4-one
Acta Crystallographica Section E
author_facet K. Rajesh
V. Vijayakumar
S. Sarveswari
T. Narasimhamurthy
Edward R. T. Tiekink
author_sort K. Rajesh
title 1-[2,4,6-Trimethyl-3,5-bis(4-oxopiperidin-1-ylmethyl)benzyl]piperidin-4-one
title_short 1-[2,4,6-Trimethyl-3,5-bis(4-oxopiperidin-1-ylmethyl)benzyl]piperidin-4-one
title_full 1-[2,4,6-Trimethyl-3,5-bis(4-oxopiperidin-1-ylmethyl)benzyl]piperidin-4-one
title_fullStr 1-[2,4,6-Trimethyl-3,5-bis(4-oxopiperidin-1-ylmethyl)benzyl]piperidin-4-one
title_full_unstemmed 1-[2,4,6-Trimethyl-3,5-bis(4-oxopiperidin-1-ylmethyl)benzyl]piperidin-4-one
title_sort 1-[2,4,6-trimethyl-3,5-bis(4-oxopiperidin-1-ylmethyl)benzyl]piperidin-4-one
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-06-01
description In the structure of the title compound, C27H39N3O3, each of the (4-oxopiperidin-1-yl)methyl residues adopts a flattened chair conformation (with the N and carbonyl groups being oriented to either side of the central C4 plane) and they occupy positions approximately orthogonal to the central benzene ring [Cbenzene—C—Cmethylene—N torsion angles 103.4 (2), −104.4 (3) and 71.9 (3)°]; further, two of these residues are oriented to one side of the central benzene ring with the third to the other side. In the crystal packing, supramolecular layers in the ab plane are sustained by C—H...O interactions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810016570
work_keys_str_mv AT krajesh 1246trimethyl35bis4oxopiperidin1ylmethylbenzylpiperidin4one
AT vvijayakumar 1246trimethyl35bis4oxopiperidin1ylmethylbenzylpiperidin4one
AT ssarveswari 1246trimethyl35bis4oxopiperidin1ylmethylbenzylpiperidin4one
AT tnarasimhamurthy 1246trimethyl35bis4oxopiperidin1ylmethylbenzylpiperidin4one
AT edwardrttiekink 1246trimethyl35bis4oxopiperidin1ylmethylbenzylpiperidin4one
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