Trichodermin (12,13-epoxytrichethec-9-en-4β-yl 4-fluorobenzoate)

Trichodermin (12,13-epoxytrichethec-9-en-4β-yl 4-fluorobenzoate)

In the title trichodermin compound (systematic name: 12,13-epoxytrichothec-9-en-4β-yl 4-fluorobenzoate), C22H25FO4, the five-membered ring displays an envelope conformation, whereas the two six-membered rings show the different conformations, viz. chair and half-chair. As for the seven-...

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Main Authors: Xu-hui Xu, Zong-cheng Wang, Jing-li Cheng, Yong Zhou, Jin-hao Zhao
Format: Article
Language:English
Published: International Union of Crystallography 2010-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810028461
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spelling doaj-76fdfde3f5f0412990ae3eced94cda862020-11-25T02:46:53ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-08-01668o2097o209710.1107/S1600536810028461Trichodermin (12,13-epoxytrichethec-9-en-4β-yl 4-fluorobenzoate)Xu-hui XuZong-cheng WangJing-li ChengYong ZhouJin-hao ZhaoIn the title trichodermin compound (systematic name: 12,13-epoxytrichothec-9-en-4β-yl 4-fluorobenzoate), C22H25FO4, the five-membered ring displays an envelope conformation, whereas the two six-membered rings show the different conformations, viz. chair and half-chair. As for the seven-membered ring, the dihedral angle between the mean planes formed by the four C atoms of the envelope unit and the three C and one O atoms of the six-membered chair is 68.67 (2)°; these two mean planes are nearly perpendicular to the epoxy ring with angles of 87.97 (2)and 88.14 (2)°, respectively. http://scripts.iucr.org/cgi-bin/paper?S1600536810028461
collection DOAJ
language English
format Article
sources DOAJ
author Xu-hui Xu
Zong-cheng Wang
Jing-li Cheng
Yong Zhou
Jin-hao Zhao
spellingShingle Xu-hui Xu
Zong-cheng Wang
Jing-li Cheng
Yong Zhou
Jin-hao Zhao
Trichodermin (12,13-epoxytrichethec-9-en-4β-yl 4-fluorobenzoate)
Acta Crystallographica Section E
author_facet Xu-hui Xu
Zong-cheng Wang
Jing-li Cheng
Yong Zhou
Jin-hao Zhao
author_sort Xu-hui Xu
title Trichodermin (12,13-epoxytrichethec-9-en-4β-yl 4-fluorobenzoate)
title_short Trichodermin (12,13-epoxytrichethec-9-en-4β-yl 4-fluorobenzoate)
title_full Trichodermin (12,13-epoxytrichethec-9-en-4β-yl 4-fluorobenzoate)
title_fullStr Trichodermin (12,13-epoxytrichethec-9-en-4β-yl 4-fluorobenzoate)
title_full_unstemmed Trichodermin (12,13-epoxytrichethec-9-en-4β-yl 4-fluorobenzoate)
title_sort trichodermin (12,13-epoxytrichethec-9-en-4β-yl 4-fluorobenzoate)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-08-01
description In the title trichodermin compound (systematic name: 12,13-epoxytrichothec-9-en-4β-yl 4-fluorobenzoate), C22H25FO4, the five-membered ring displays an envelope conformation, whereas the two six-membered rings show the different conformations, viz. chair and half-chair. As for the seven-membered ring, the dihedral angle between the mean planes formed by the four C atoms of the envelope unit and the three C and one O atoms of the six-membered chair is 68.67 (2)°; these two mean planes are nearly perpendicular to the epoxy ring with angles of 87.97 (2)and 88.14 (2)°, respectively.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810028461
work_keys_str_mv AT xuhuixu trichodermin1213epoxytrichethec9en4amp946yl4fluorobenzoate
AT zongchengwang trichodermin1213epoxytrichethec9en4amp946yl4fluorobenzoate
AT jinglicheng trichodermin1213epoxytrichethec9en4amp946yl4fluorobenzoate
AT yongzhou trichodermin1213epoxytrichethec9en4amp946yl4fluorobenzoate
AT jinhaozhao trichodermin1213epoxytrichethec9en4amp946yl4fluorobenzoate
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