catena-Poly[[aquadipyridinecopper(II)]-μ-fumarato]
The title compound, [Cu(C4H2O4)(C5H5N)2(H2O)]n, is a one-dimensional coordination polymer based on pyridine and fumarate ligands. Each CuII cation is coordinated by two carboxylate O atoms belonging to two fumarate anions, two N atoms from two pyridine molecules and one water molecule, in a square-b...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-01-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536807063738 |
| Summary: | The title compound, [Cu(C4H2O4)(C5H5N)2(H2O)]n, is a one-dimensional coordination polymer based on pyridine and fumarate ligands. Each CuII cation is coordinated by two carboxylate O atoms belonging to two fumarate anions, two N atoms from two pyridine molecules and one water molecule, in a square-based pyramidal geometry. Each fumarate anion bridges two CuII cations through the two carboxylate groups in a bis-monodentate fashion to form a one-dimensional polymeric chain along the c axis. Neighbouring chains are linked together to form a two-dimensional network parallel to the ac plane via hydrogen bonding interactions between uncoordinated carboxylate O atoms and coordinated water molecules of adjecent chains. |
|---|---|
| ISSN: | 1600-5368 |